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Merck
CN

B73104

1-Bromonaphthalene

97%

Synonym(s):

1-Naphthyl bromide

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About This Item

Empirical Formula (Hill Notation):
C10H7Br
CAS Number:
90-11-9
Molecular Weight:
207.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24891985
EC Number:
201-965-2
Beilstein/REAXYS Number:
1906414
MDL number:
MFCD00003868

Key Documents

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Product Name

1-Bromonaphthalene, 97%

SMILES string

Brc1cccc2ccccc12

InChI key

DLKQHBOKULLWDQ-UHFFFAOYSA-N

InChI

1S/C10H7Br/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H

assay

97%

form

liquid

refractive index

n20/D 1.6570 (lit.)

bp

133-134 °C/10 mmHg (lit.)

mp

−2-−1 °C (lit.)

density

1.48 g/mL at 20 °C (lit.)

Quality Level

200

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Application

1-Bromonaphthalene is a bromoarene that can be used in:
  • Palladium-catalyzed Suzuki–Miyaura coupling reaction with potassium aryltrifluoroborates without the use of phase-transfer catalysts or phosphine ligands.
  • The preparation of indeno annelated polycyclic aromatic hydrocarbons by reacting with o-bromobenzeneboronic acid and oligocyclic bromoarenes via Suzuki-Heck type coupling.
  • Ni catalyzed Kumada–Tamao–Corriu cross-coupling reaction with PhMgBr.
  • The preparation of arylnaphthalenes via palladium-catalyzed Suzuki-Miyaura cross-coupling reaction with aryl boronic acid.

General description

1-Bromonaphthalene serves as an intermediate for the synthesis of biaryl compounds via cross-coupling reactions.

pictograms

Exclamation markEnvironment
GHS07,GHS09

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN8724
BCCM4240
BCCK3446
BCCL2355
BCCH3693

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High efficiency of cavity-based triaryl-phosphines in nickel-catalysed Kumada-Tamao-Corriu cross-coupling
Monnereau L, et al.
Chemical Communications (Cambridge, England), 47(23), 6626-6628 (2011)
Exploring the selectivity of the Suzuki-Miyaura cross-coupling reaction in the synthesis of arylnaphthalenes
Lima CFRAC, et al.
Tetrahedron, 67(4), 689-697 (2011)
Microwave-accelerated Suzuki-Miyaura coupling reactions using potassium aryltrifluoroborates
Harker RL and Crouch RD
Synthesis, 2007(01), 25-27 (2007)
Xinzhen Du et al.
Journal of colloid and interface science, 274(2), 645-651 (2004-05-18)
The binding of polyethylene glycol (10) n-octylphenyl ether (OPE) and polyethylene glycol (10) tert-octylphenyl ether (Triton X-100, TX) to beta-cyclodextrin (beta-CD) and heptakis(2,3- beta-dimethyl)- beta-CD (DM- beta-CD) was described in detail by surface tension, steady-state fluorescence of OPE and TX
A New Suzuki- Heck-Type Coupling Cascade: Indeno [1, 2, 3]-Annelation of Polycyclic Aromatic Hydrocarbons
Wegner HA, et al.
The Journal of Organic Chemistry, 68(3), 883-887 (2003)
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