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Merck
CN

B92001

4-tert-Butylcyclohexanol, mixture of cis and trans

98%

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About This Item

Linear Formula:
(CH3)3CC6H10OH
CAS Number:
Molecular Weight:
156.27
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-676-4
Beilstein/REAXYS Number:
1902277
MDL number:
Assay:
98%
Form:
powder
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assay

98%

form

powder

bp

110-115 °C/15 mmHg (lit.)

mp

62-70 °C (lit.)

SMILES string

CC(C)(C)C1CCC(O)CC1

InChI

1S/C10H20O/c1-10(2,3)8-4-6-9(11)7-5-8/h8-9,11H,4-7H2,1-3H3

InChI key

CCOQPGVQAWPUPE-UHFFFAOYSA-N

Application

4-tert-Butylcyclohexanol (mixture of cis and trans) can be used as a reactant to synthesize tris(4,4′-di-tert-butyl-2,2′-bipyridine)(trans-4-tert-butylcyclohexanolato)deca-μ-oxido-heptaoxidoheptavanadium oxide cluster complex by reacting with [V8O20(C18H24N2)4]. It can also be used as a reactant in competitive Oppenauer oxidation experiments in the presence of zeolite BEA as a stereoselective catalyst. Only cis-isomer is selectively converted to the corresponding ketone, whereas trans-isomer remains unchanged.


pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

221.0 °F - closed cup

flash_point_c

105 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)



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