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Merck
CN

CDS019977

Aldol

AldrichCPR

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About This Item

Empirical Formula (Hill Notation):
C4H8O2
Molecular Weight:
88.11
UNSPSC Code:
12352200
PubChem Substance ID:
EC Number:
203-530-2
MDL number:
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InChI key

HSJKGGMUJITCBW-UHFFFAOYSA-N

InChI

1S/C4H8O2/c1-4(6)2-3-5/h3-4,6H,2H2,1H3

SMILES string

CC(O)CC=O

form

liquid

Other Notes

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

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Danger

hcodes

Hazard Classifications

Acute Tox. 2 Dermal - Eye Irrit. 2

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品
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Naoki Ishida et al.
Angewandte Chemie (International ed. in English), 57(35), 11399-11403 (2018-07-19)
An electronically neutral 2-arylsilacyclobutane generates a nucleophilic carbanion at room temperature through cleavage of the benzylic C-Si bond when simply dissolved in polar aprotic solvents such as N,N-dimethylformamide (DMF). The nucleophilic species is capable of capturing carbon dioxide to furnish
Christian Merten et al.
The Journal of organic chemistry, 84(14), 8797-8814 (2019-05-03)
Vibrational circular dichroism (VCD) spectroscopy is one of the most powerful techniques for the determination of absolute configurations (AC), as it does not require any specific UV/vis chromophores, no chemical derivatization, and no growth of suitable crystals. In the past
Rocco Moretti et al.
Protein science : a publication of the Protein Society, 27(1), 259-268 (2017-09-30)
The Rosetta molecular modeling software package provides a large number of experimentally validated tools for modeling and designing proteins, nucleic acids, and other biopolymers, with new protocols being added continually. While freely available to academic users, external usage is limited
Nicolò Santi et al.
Molecules (Basel, Switzerland), 25(10) (2020-05-30)
In this report, the streptavidin-biotin technology was applied to enable organocatalytic aldol addition. By attaching pyrrolidine to the valeric motif of biotin and introducing it to streptavidin (Sav), a protein-based organocatalytic system was created, and the aldol addition of acetone
Martha A Grover et al.
Life (Basel, Switzerland), 9(3) (2019-07-04)
Living systems employ both covalent chemistry and physical assembly to achieve complex behaviors. The emerging field of systems chemistry, inspired by these biological systems, attempts to construct and analyze systems that are simpler than biology, while still embodying biological design

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