D216402
2,2′-Dipyridylamine
98%
Synonym(s):
bipyam
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About This Item
Empirical Formula (Hill Notation):
C10H9N3
CAS Number:
Molecular Weight:
171.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-864-3
Beilstein/REAXYS Number:
127131
MDL number:
Product Name
2,2′-Dipyridylamine, 98%
InChI key
HMMPCBAWTWYFLR-UHFFFAOYSA-N
InChI
1S/C10H9N3/c1-3-7-11-9(5-1)13-10-6-2-4-8-12-10/h1-8H,(H,11,12,13)
SMILES string
N(c1ccccn1)c2ccccn2
assay
98%
form
solid
bp
222 °C/50 mmHg (lit.)
mp
90-92 °C (lit.)
Quality Level
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Application
2,2′-Dipyridylamine (bipyam) can be used:
- As a bidentate N-donor ligand in the synthesis of various metal complexes.
- To synthesize Pd-polyoxovanadates, heterogeneous catalyst for the oxidation of benzylic hydrocarbons.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Faith E Jacobsen et al.
Chembiochem : a European journal of chemical biology, 9(13), 2087-2095 (2008-07-31)
The desire to inhibit zinc-dependent matrix metalloproteinases (MMPs) has, over the course of the last 30 years, led to the development of a plethora of MMP inhibitors that bind directly to the active-site metal. With one exception, all of these
Matthew C Parrott et al.
Journal of the American Chemical Society, 131(8), 2906-2916 (2009-02-26)
A series of aliphatic polyester dendrons, generations 1 through 8, were prepared with a core p-toluenesulfonyl ethyl (TSe) ester as an easily removable protecting group that can be efficiently replaced with a variety of nucleophiles. Using amidation chemistry, a tridentate
Three Pd-decavanadates with a controllable molar ratio of Pd to decavanadate and their heterogeneous aerobic oxidation of benzylic C-H bonds
Huang X, et al.
Dalton Transactions, 47(3), 726-733 (2018)
Runyu Tan et al.
Inorganic chemistry, 51(13), 7039-7049 (2012-06-13)
A novel multidentate ligand with 2,2'-dipyridylamine functionalities, 1,8-bis[4-(2,2'-dipyridylamino)phenylacetylenyl]anthracene (1), has been synthesized through a double Sonogashira coupling reaction and characterized by NMR spectroscopic, elemental, and X-ray diffraction analyses. Compound 1 can bind to either one metal center as a tetradentate
John J Allen et al.
Dalton transactions (Cambridge, England : 2003), (5)(5), 878-890 (2009-01-22)
Complexes of the type [Cu(H-dpa)(olefin)]BF4 for ethylene (1), propylene (2), 1-butene (3), 1-hexene (4), 1-octene (5), cis-2-octene (6), trans-2-octene (7), cis-3-octene (8), trans-3-octene (9), 2-norbornylene (10), 1,5-cyclooctadiene (11), styrene (12), cis-stilbene (13), trans-stilbene (14), and Ph2C=CH2 (15) have been prepared
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