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D35457

N,N-Dibenzylhydroxylamine

Name: <I>N</I>,<I>N</I>-Dibenzylhydroxylamine
Brand: ALDRICH

98%

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About This Item

Linear Formula:

(C₆H₅CH₂)₂NOH

CAS Number:

621-07-8

Molecular Weight:

213.28

NACRES:

NA.22

PubChem Substance ID:

24893768

UNSPSC Code:

12352100

EC Number:

210-667-1

MDL number:

MFCD00004772

Assay:

98%

Form:

crystals

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Properties

Quality Level

100

assay

98%

form

crystals

mp

125-128 °C (lit.)

SMILES string

ON(Cc1ccccc1)Cc2ccccc2

InChI

1S/C14H15NO/c16-15(11-13-7-3-1-4-8-13)12-14-9-5-2-6-10-14/h1-10,16H,11-12H2

InChI key

GXELTROTKVKZBQ-UHFFFAOYSA-N

Description

Application

N,N-Dibenzylhydroxylamine, upon oxidation, yields N-benzyl-α-phenylnitrone, which can undergo cycloaddition reaction with suitable dipolarophiles. It can be used to synthesize N,N,O-trisubstituted hydroxylamines and arylamines.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Mechanistic studies lead to dramatically improved reaction conditions for the Cu-catalyzed asymmetric hydroamination of olefins.

Bandar JS, et al.

Journal of the American Chemical Society, 137(46), 14812-14818 (2015)

Synthesis of N,N,O-Trisubstituted Hydroxylamines by Stepwise Reduction and Substitution of O-Acyl N, N-Disubstituted Hydroxylamines.

Dhanju S and Crich D

Organic Letters, 18(8), 1820-1823 (2016)

Synthesis of Arylamines via Aminium Radicals.

Svejstrup TD, et al.

Angewandte Chemie (International Edition in English), 56(47), 14948-14952 (2017)

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Global Trade Item Number

SKU	GTIN
D35457-5G	04061833563328