D36550
Dibenzyl phosphate
99%
Synonym(s):
DBzP
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About This Item
Linear Formula:
(C6H5CH2O)2P(O)(OH)
CAS Number:
Molecular Weight:
278.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-602-3
Beilstein/REAXYS Number:
2055755
MDL number:
Product Name
Dibenzyl phosphate, 99%
InChI key
HDFFVHSMHLDSLO-UHFFFAOYSA-N
InChI
1S/C14H15O4P/c15-19(16,17-11-13-7-3-1-4-8-13)18-12-14-9-5-2-6-10-14/h1-10H,11-12H2,(H,15,16)
SMILES string
OP(=O)(OCc1ccccc1)OCc2ccccc2
assay
99%
form
powder
mp
78-80 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
Dibenzyl phosphate (DBzP) can be used:
- To promote the monoselective ortho-C-H alkylation of N-quinolyl benzamides with primary and secondary alkyl iodides.
- For the ring-opening reaction of epoxide such as benzylglycidol to synthesize dihydroxyacetone phosphate (DHAP).
- As a reactant for the synthesis of stereospecific 1,2-trans glycosyl phosphates.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Biosynthetic studies on the ?-glucosidase inhibitor acarbose: the chemical synthesis of dTDP-4-amino-4, 6-dideoxy-?-d-glucose.
Bowers SG, et al.
Carbohydrate Research, 337(4), 297-304 (2002)
Pd-Catalyzed Monoselective ortho-C-H Alkylation of N-Quinolyl Benzamides: Evidence for Stereoretentive Coupling of Secondary Alkyl Iodides.
Zhang SY, et al.
Journal of the American Chemical Society, 137(1), 531-539 (2014)
An approach towards the synthesis of 1, 2-trans glycosyl phosphates via iodonium ion assisted activation of thioglycosides.
Veeneman GH, et al.
Tetrahedron Letters, 32(43), 6175-6178 (1991)
Lewis acid mediated regioselective ring opening of benzylglycidol with dibenzyl phosphate: short and attractive synthesis of dihydroxyacetone phosphate.
Meyer O, et al.
Organic Letters, 8(19), 4347-4350 (2006)
Syntheses of glycosyl phosphates by phase transfer catalysis.
Roy R, et al.
Canadian Journal of Chemistry, 69(9), 1462-1467 (1991)
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