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About This Item
Empirical Formula (Hill Notation):
Sm
CAS Number:
Molecular Weight:
150.36
MDL number:
UNSPSC Code:
12141612
PubChem Substance ID:
NACRES:
NA.23
Assay
≥99%
form
rod
manufacturer/tradename
Goodfellow 988-838-48
resistivity
91.4 μΩ-cm, 0°C
bp
1794 °C (lit.)
mp
1074 °C (lit.)
density
7.47 g/mL at 25 °C (lit.)
SMILES string
[Sm]
InChI
1S/Sm
InChI key
KZUNJOHGWZRPMI-UHFFFAOYSA-N
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General description
For updated SDS information please visit www.goodfellow.com.
Legal Information
Product of Goodfellow
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Water-react 3
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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Samarium(II)-iodide-mediated cyclizations in natural product synthesis.
David J Edmonds et al.
Chemical reviews, 104(7), 3371-3404 (2004-07-15)
Pete Anderson et al.
Expert review of anticancer therapy, 7(11), 1517-1527 (2007-11-21)
Radiation therapy can be an effective means to treat bone metastases, which occur in more than 50% of cancer patients. (153)Samarium lexidronam ((153)Sm-EDTMP; Quadramet, Cytogen) is a radiopharmaceutical designed for deposition into bone metastases. Bone scans can identify patients that
Michal Szostak et al.
Chemical communications (Cambridge, England), 48(3), 330-346 (2011-09-01)
Samarium diiodide (SmI(2)) is one of the most important reductive electron transfer reagents available in the laboratory. Key to the popularity of SmI(2) is the ability of additives and co-solvents to tune the properties of the reagent. Over the last
Michal Szostak et al.
Organic letters, 16(19), 5052-5055 (2014-09-24)
The first general method for the chemoselective synthesis of α,α-dideuterio alcohols directly from feedstock carboxylic acids under single electron transfer conditions using SmI2 is reported. This reaction proceeds after the activation of Sm(II) with a Lewis base, results in excellent
José M Concellón et al.
Chemical Society reviews, 39(11), 4103-4113 (2010-08-05)
Samarium metal and samarium diiodide have become important tools as selective cyclopropanating agents in organic synthesis due to their high chemo- and stereoselectivity. Therefore, Sm and SmI(2) are the ideal reagents to prepare cyclopropane derivatives. This tutorial review highlights C-C
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