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About This Item
Linear Formula:
LiAlH[OC(CH3)3]3
CAS Number:
Molecular Weight:
254.27
UNSPSC Code:
12352000
NACRES:
NA.22
PubChem Substance ID:
EC Number:
241-490-8
Beilstein/REAXYS Number:
5796791
MDL number:
Assay:
97%
Quality Segment
assay
97%
reaction suitability
reagent type: reductant
mp
300-319 °C (dec.) (lit.)
SMILES string
[H][Al]([Li])(OC(C)(C)C)(OC(C)(C)C)OC(C)(C)C
InChI
1S/3C4H9O.Al.Li.H/c3*1-4(2,3)5;;;/h3*1-3H3;;;/q3*-1;+2;+1;
InChI key
BYBIDFZFKATBFH-UHFFFAOYSA-N
Application
Lithium tri-tert-butoxyaluminum hydride (LTBA) is a stable, mild reducing agent that is used to selectively reduce aldehydes and ketones in the presence of esters. It can also be used to reduce imidoyl chlorides to aldimines and aromatic disulfides to the corresponding thiols.
- Reducing agent
Signal Word
Danger
Hazard Codes
Precautionary Statements
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
PPE (personal protective equipment)
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - Water-react. 1
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