L511838
[Ir(dtbbpy)(ppy)2][PF6]
AldrichCPR
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About This Item
Empirical Formula (Hill Notation):
C40H40F6IrN4P
CAS Number:
Molecular Weight:
913.95
PubChem Substance ID:
UNSPSC Code:
12352200
reaction suitability
reagent type: catalyst
reaction type: C-H Activation
SMILES string
CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F
InChI
1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;
InChI key
DZARMRZNOUWGQE-UHFFFAOYSA-N
Application
Catalyst for the visible-light mediated formation of alpha-amino radicals, used by Nishibayashi for addition into electron-poor alkenes and imines
Visible-Light-Mediated Utilization of ·-Aminoalkyl Radicals: Addition to Electron-Deficient Alkenes Using Photoredox Catalysts
In presence of [Co(bpy)3]2+, serves as photosensitizer for H2 generation from water (water splitting).
Tricyclometalated Iridium Complexes as Highly Stable Photosensitizers for Light-Induced Hydrogen Evolution
For other Visible-Light Photocatalysts, refer to: www.aldrich.com/photocatalysis
Visible-Light-Mediated Utilization of ·-Aminoalkyl Radicals: Addition to Electron-Deficient Alkenes Using Photoredox Catalysts
In presence of [Co(bpy)3]2+, serves as photosensitizer for H2 generation from water (water splitting).
Tricyclometalated Iridium Complexes as Highly Stable Photosensitizers for Light-Induced Hydrogen Evolution
For other Visible-Light Photocatalysts, refer to: www.aldrich.com/photocatalysis
Other Notes
Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.
NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.
NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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