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Merck
CN

L512036

Sigma-Aldrich

TFB

AldrichCPR

Synonym(s):

Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,4′-(N-(4-sec-butylphenyl)diphenylamine)]

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About This Item

Linear Formula:
(C51H61N)n
CAS Number:
UNSPSC Code:
12352200
PubChem Substance ID:
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SMILES string

CCCCCCCCC1(CCCCCCCC)C2=C(C=CC(C3=CC=C(N(C4=CC=C(C(CC)C)C=C4)C5=CC=C(C)C=C5)C=C3)=C2)C6=C1C=C(C)C=C6

InChI

1S/C53H67N/c1-7-10-12-14-16-18-36-53(37-19-17-15-13-11-8-2)51-38-41(5)22-34-49(51)50-35-27-45(39-52(50)53)44-25-32-48(33-26-44)54(46-28-20-40(4)21-29-46)47-30-23-43(24-31-47)42(6)9-3/h20-35,38-39,42H,7-19,36-37H2,1-6H3

InChI key

LMXSDGRJIJNLIY-UHFFFAOYSA-N

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General description

TFB is an ambipolar polymer that is majorly used as a hole transporting layer (HTL). It has a band gap of ∼2.7 eV and can act as an electron dominant polymer.

Application

TFB can be used for a variety of optoelectronic applications such as organic light emitting diodes (OLEDs), quantum dot displays (QDs) and solar cells.

Other Notes

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

Storage Class Code

13 - Non Combustible Solids

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Aya Umeno et al.
PloS one, 8(5), e63542-e63542 (2013-05-22)
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Scientific reports, 9(1), 10385-10385 (2019-07-19)
In this study, we introduce optimization of the annealing conditions for improvement of hardness and hole transporting properties of high-molecular weight poly [9, 9-dioctylfluorene-co-N-(4-(3-methylpropyl)) diphenylamine] (TFB) film used as a Hole Transport Layer (HTL) of Quantum-dot Light-emitting Diodes (QLEDs). As
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Articles

Organic Light-emitting Diodes (OLEDs) are solid-state devices that transform electrical energy into light. OLEDs are considered the next generation technology for high-resolution flexible displays and solid state lighting, attracting intense scientific and industrial interest.

Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

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