M28006
(Methylamino)acetaldehyde dimethyl acetal
97%
Synonym(s):
1,1-Dimethoxy-2-methylaminoethane, 2,2-Dimethoxy-N-methylethylamine
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About This Item
Linear Formula:
CH3NHCH2CH(OCH3)2
CAS Number:
Molecular Weight:
119.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-520-0
Beilstein/REAXYS Number:
605322
MDL number:
Assay:
97%
Form:
liquid
InChI
1S/C5H13NO2/c1-6-4-5(7-2)8-3/h5-6H,4H2,1-3H3
InChI key
HUMIEJNVCICTPJ-UHFFFAOYSA-N
SMILES string
CNCC(OC)OC
assay
97%
form
liquid
refractive index
n20/D 1.414 (lit.)
bp
140 °C (lit.)
density
0.928 g/mL at 25 °C (lit.)
Quality Level
Related Categories
Application
(Methylamino)acetaldehyde dimethyl acetal can be used as a reactant to synthesize:
- Aza[3.3.2] cyclazines by reacting with 5-methyloxazolo[3,2-a]pyridinium salts via synthesis of functionalized 5-aminoindolizines intermediates.
- N-(2,2-Dimethoxyethyl)-N-methyl-3,4-dimethoxyphenylglycine by Petasis reaction with glyoxylic acid and 3,4-dimethoxyphenylboronic acid.
- Substituted imidazoles via copper-catalyzed reaction with various nitriles.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
84.2 °F
flash_point_c
29 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Expedient synthesis of substituted imidazoles from nitriles
Frutos RP, et al.
Tetrahedron Letters, 46(48), 8369-8372 (2005)
Rearrangement of oxazolo [3, 2-a] pyridines as an approach of synthesizing aza [3.3. 2] cyclazines
Babaev EV, et al.
Chemistry of Heterocyclic Compounds, 51(3), 269-274 (2015)
A concise synthesis of tetrahydroisoquinoline-1-carboxylic acids using a Petasis reaction and Pomeranz-Fritsch-Bobbitt cyclization sequence
Chrzanowska M, et al.
Tetrahedron, 68(14), 3092-3097 (2012)
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