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Merck
CN

M46705

N-Methylformamide

99%

Synonym(s):

N-Formylmethylamine

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About This Item

Linear Formula:
HCONHCH3
CAS Number:
Molecular Weight:
59.07
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
204-624-6
Beilstein/REAXYS Number:
1098352
MDL number:
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Product Name

N-Methylformamide, 99%

InChI key

ATHHXGZTWNVVOU-UHFFFAOYSA-N

InChI

1S/C2H5NO/c1-3-2-4/h2H,1H3,(H,3,4)

SMILES string

[H]C(=O)NC

assay

99%

form

liquid

refractive index

n20/D 1.432 (lit.)

bp

198-199 °C (lit.)

mp

−4 °C (lit.)

density

1.011 g/mL at 25 °C (lit.)

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Legal Information

DuPont product

pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Repr. 1B

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

231.8 °F - closed cup

flash_point_c

111 °C - closed cup


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Jolanta Swiergiel et al.
The journal of physical chemistry. B, 113(43), 14225-14228 (2009-10-07)
Impedance spectroscopy was used for studies of the frequency dependence of the electric conductivity of two highly conducting liquid amides: N-methylformamide (NMF), strongly self-associated via the hydrogen bonds C=O...N-H, and N,N-dimethylformamide (DMF), which is not able to self-organize by hydrogen
Jeppe S Spicker et al.
Toxicological sciences : an official journal of the Society of Toxicology, 102(2), 444-454 (2008-01-08)
A large number of databases are currently being implemented within toxicology aiming to integrate diverse biological data, such as clinical chemistry, expression, and other types of data. However, for these endeavors to be successful, tools for integration, visualization, and interpretation
Edward M Kosower et al.
The journal of physical chemistry. B, 113(16), 5622-5632 (2009-03-31)
N-methylformamide (NMF), the simplest model for peptides, exhibits hyperplectic (both simple and complex) behavior as revealed by thin film infrared spectroscopy on planar AgX [AgCl:AgBr] fiber. IR spectra (0.1 s scans) of 10 microg NMF/dichloromethane(DCM) under N(2) flow first show
Walther Caminati et al.
Physical chemistry chemical physics : PCCP, 12(35), 10230-10234 (2010-07-27)
We investigated the Fourier transform microwave spectra of the hydrated forms of N-methylformamide (NMF) in a supersonic expansion and assigned the rotational spectra of two mono-hydrated species. The conformation of each molecular complex was reliably determined on the basis of
Rachel Crespo-Otero et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 14(4), 827-836 (2012-10-04)
The photochemistry of N-methylformamide (MF) is elucidated by investigating its photodissociation products generated by UV irradiation (248 nm) in an argon matrix (10 K). We find that, starting from trans-MF, prolonged irradiation produces cis-MF, CH3NH2 and CO fragments as major

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