M50001
Methylhydrazine
98%
Synonym(s):
MMH
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About This Item
Linear Formula:
CH3NHNH2
CAS Number:
Molecular Weight:
46.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-471-4
Beilstein/REAXYS Number:
635645
MDL number:
Assay:
98%
vapor density
1.6 (vs air)
vapor pressure
37.5 mmHg ( 20 °C)
assay
98%
autoignition temp.
385 °F
expl. lim.
97 %
refractive index
n20/D 1.4325 (lit.)
bp
88-90 °C (lit.)
density
0.875 g/mL at 20 °C (lit.)
SMILES string
CNN
InChI
1S/CH6N2/c1-3-2/h3H,2H2,1H3
InChI key
HDZGCSFEDULWCS-UHFFFAOYSA-N
Application
Methylhydrazine can be used to induce asymmetric aerobic epoxidation of β-trifluoromethyl-β,β-disubstituted enones to synthesize enantioselective trifluoromethyl-substituted epoxides. It can also be used to synthesize 1-methyl-3,5-dinitro-1H-1,2,4-triazole (DNMT), a substitute for TNT explosive.
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Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
flash_point_f
17.6 °F - closed cup
flash_point_c
-8 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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J M Pujolar et al.
BMC genomics, 16, 600-600 (2015-08-14)
Species showing complex life cycles provide excellent opportunities to study the genetic associations between life cycle stages, as selective pressures may differ before and after metamorphosis. The European eel presents a complex life cycle with two metamorphoses, a first metamorphosis
A safe and scalable process for the synthesis of melt-cast explosive 1-methyl-3, 5-dinitro-1H-1, 2, 4-triazole.
Luo J, et al.
Chemistry of Heterocyclic Compounds, 53(6-7), 714-718 (2017)
Enantioselective Synthesis of Epoxides Having a Tetrasubstituted Trifluoromethylated Carbon Center: Methylhydrazine-Induced Aerobic Epoxidation of β, β-Disubstituted Enones.
Kawai H, et al.
Angewandte Chemie (International ed. in English), 125(8), 2277-2281 (2013)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| M50001-100G | 04061836831035 |
| M50001-25G | 04061836831042 |