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M80806

4-Methylstyrene

Name: 4-Methylstyrene
Brand: ALDRICH

96%, contains 3,5-di-tert-butylcatechol as inhibitor

Synonym(s):

4-Vinyltoluene

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About This Item

Linear Formula:

CH₃C₆H₄CH=CH₂

CAS Number:

622-97-9

Molecular Weight:

118.18

UNSPSC Code:

12162002

NACRES:

NA.23

PubChem Substance ID:

24897220

EC Number:

210-762-8

Beilstein/REAXYS Number:

1209317

MDL number:

MFCD00008621

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Properties

vapor pressure

<1 mmHg ( 20 °C)

Quality Level

100

assay

96%

form

liquid

autoignition temp.

959 °F

contains

3,5-di-tert-butylcatechol as inhibitor

expl. lim.

5.3 %

refractive index

n20/D 1.542 (lit.)

bp

170-175 °C (lit.)

density

0.897 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

Cc1ccc(C=C)cc1

InChI

1S/C9H10/c1-3-9-6-4-8(2)5-7-9/h3-7H,1H2,2H3

InChI key

JLBJTVDPSNHSKJ-UHFFFAOYSA-N

Description

General description

4-Methylstyrene is a molecule with an extended Π conjugation. The threefold symmetric torsional potential of 4-methylstyrene has been investigated. Polymerization of 4-methylstyrene by employing a half-metallocene type catalytic system composed of (trimethyl)pentamethylcyclopentadienyltitanium (Cp*TiMe₃), trioctylaluminum (AlOct₃), and tris(pentafluorophenyl)borane [B(C₆F₅)₃] has been reported. Palladium-catalyzed Heck coupling of chlorobenzene with 4-methylstyrene has been investigated.

Application

4-Methylstyrene was employed as Π ligand in the preparation of cationic, two-coordinate triphenylphosphine-gold(I)-Π complexes.

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pictograms

GHS02,GHS08,GHS09

signalword

Danger

hcodes

H226,H304,H411

pcodes

P210 - P233 - P240 - P273 - P301 + P310 - P331

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

113.0 °F

flash_point_c

45 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Synthesis and study of cationic, two-coordinate triphenylphosphine-gold-π complexes.

Rachel E M Brooner et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 19(25), 8276-8284 (2013-04-18)

Cationic, two-coordinate triphenylphosphine-gold(I)-π complexes of the form [(PPh₃)Au(π ligand)]⁺SbF₆⁻ (π ligand=4-methylstyrene, 1∙SbF₆), 2-methyl-2-butene (3∙SbF₆), 3-hexyne (6∙SbF₆), 1,3-cyclohexadiene (7∙SbF₆), 3-methyl-1,2-butadiene (8∙SbF₆), and 1,7-diphenyl-3,4-heptadiene (10∙SbF₆) were generated in situ from reaction of [(PPh₃)AuCl], AgSbF₆, and π ligand at -78 °C and were

Syndiospecific living polymerization of 4-methylstyrene and styrene with (trimethyl) pentamethylcyclopentadienyltitanium/tris (pentafluorophenyl) borane/trioctylaluminum catalytic system.

Kawabe M and Murata M.

Journal of Polymer Science Part A: Polymer Chemistry, 39(21), 3692-3706 (2001)

An efficient palladium-catalyzed Heck coupling of aryl chlorides with alkenes.

Yi C and Hua R.

Tetrahedron Letters, 47(15), 2573-2576 (2006)

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Global Trade Item Number

SKU	GTIN
M80806-500ML	04061834062721
M80806-10ML	04061837835773
M80806-100ML	04061837835766