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P10801

Perinaphthenone

Name: Perinaphthenone
Brand: ALDRICH

97%

Synonym(s):

1H-Benzonaphthen-1-one, 7-Perinaphthenone, Phenalenone, Phenalone

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About This Item

Empirical Formula (Hill Notation):

C₁₃H₈O

CAS Number:

548-39-0

Molecular Weight:

180.20

NACRES:

NA.22

PubChem Substance ID:

24898151

UNSPSC Code:

12352100

EC Number:

208-945-2

MDL number:

MFCD00004143

Assay:

97%

Form:

powder

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Properties

Quality Level

100

assay

97%

form

powder

mp

153-156 °C (lit.)

SMILES string

O=C1C=Cc2cccc3cccc1c23

InChI

1S/C13H8O/c14-12-8-7-10-4-1-3-9-5-2-6-11(12)13(9)10/h1-8H

InChI key

WWBGWPHHLRSTFI-UHFFFAOYSA-N

Description

Application

Perinaphthenone can be used:

In the Weitz-Scheffer epoxidation to produce the corresponding epoxides in the presence of gem-dihydroperoxide as the stoichiometric oxidant.
As a photosensitizer in the photodegradation of tebuconazole.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Histochemical analysis of phenylphenalenone-related compounds in Xiphidium caeruleum (Haemodoraceae).

S Opitz et al.

Planta, 216(5), 881-889 (2003-03-08)

Phenylphenalenones represent a typical group of secondary metabolites of the Haemodoraceae. Some of these phenolic compounds show organ-specific distribution within the plant. However, detailed information on cellular localisation is still lacking. To this end, confocal laser-scanning microscopy, microspectral photometry and

Fungal phenalenones: chemistry, biology, biosynthesis and phylogeny.

Mahmoud F Elsebai et al.

Natural product reports, 31(5), 628-645 (2014-04-02)

Covering up to the end of August 2013. Phenalenones are members of a unique class of natural polyketides exhibiting diverse biological potential. This is a comprehensive review of 72 phenalenones with diverse structural features originating from fungal sources. Their bioactive

Palladium catalyzed bicyclization of 1,8-diiodonaphthalene and tertiary propargylic alcohols to phenalenones and their applications as fluorescent chemosensor for fluoride ions.

Xiaopeng Chen et al.

Chemical communications (Cambridge, England), 47(9), 2628-2630 (2011-01-15)

Phenalenone derivatives were efficiently constructed from 1,8-diiodonaphthalene and tertiary propynols via a one-pot domino reaction which eventually included Pd-catalyzed Sonogoshira coupling, Pd-catalyzed allylic oxidation and Pd-catalyzed C(sp(2))-H activation. Moreover, the synthesized phenalenone derivative presented a practical application as a fluorescent

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Global Trade Item Number

SKU	GTIN
P10801-1G	04061834353959