P22389
Phenyl dichlorophosphate
≥95%
Synonym(s):
Phenyl phosphodichloridate, Phenyl phosphorodichloridate, Phenyl phosphoryl dichloride
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About This Item
Linear Formula:
C6H5OP(O)Cl2
CAS Number:
Molecular Weight:
210.98
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-220-6
Beilstein/REAXYS Number:
511863
MDL number:
Assay:
≥95%
Quality Level
assay
≥95%
refractive index
n20/D 1.523 (lit.)
bp
241-243 °C (lit.)
density
1.412 g/mL at 25 °C (lit.)
SMILES string
ClP(Cl)(=O)Oc1ccccc1
InChI
1S/C6H5Cl2O2P/c7-11(8,9)10-6-4-2-1-3-5-6/h1-5H
InChI key
TXFOLHZMICYNRM-UHFFFAOYSA-N
Application
Reagent for the preparation of phosphate diesters.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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The Journal of Organic Chemistry, 53, 2077-2077 (1988)
Chun-Wei Kuo et al.
Molecules (Basel, Switzerland), 17(11), 13662-13672 (2012-11-22)
Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.
Xiaoming Zhou et al.
Chemosphere, 235, 163-168 (2019-07-01)
Two novel phosphorus-containing copolyesters were synthesized by direct polycondensation reaction of phenyl dichlorophosphate, 1,4-succinic acid and 1,4-butanediol using stannous chloride (SnCl2) and 4-Methylbenzenesulfonic acid as catalyst, and its chemical structures were identified by 1H and 31P nuclear magnetic resonances (1H
Global Trade Item Number
| SKU | GTIN |
|---|---|
| P22389-25G | 04061838124517 |
| P22389-100G | 04061834362784 |