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Merck
CN

P22389

Phenyl dichlorophosphate

≥95%

Synonym(s):

Phenyl phosphodichloridate, Phenyl phosphorodichloridate, Phenyl phosphoryl dichloride

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About This Item

Linear Formula:
C6H5OP(O)Cl2
CAS Number:
770-12-7
Molecular Weight:
210.98
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24898297
EC Number:
212-220-6
Beilstein/REAXYS Number:
511863
MDL number:
MFCD00002067
Assay:
≥95%

Key Documents

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Product Name

Phenyl dichlorophosphate, ≥95%

InChI key

TXFOLHZMICYNRM-UHFFFAOYSA-N

InChI

1S/C6H5Cl2O2P/c7-11(8,9)10-6-4-2-1-3-5-6/h1-5H

SMILES string

ClP(Cl)(=O)Oc1ccccc1

assay

≥95%

refractive index

n20/D 1.523 (lit.)

bp

241-243 °C (lit.)

density

1.412 g/mL at 25 °C (lit.)

Quality Level

200

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Related Categories

Application

Reagent for the preparation of phosphate diesters.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
STBJ7558
STBF6200V
STBC6044V
STBC6847V
STBC6484V

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The Journal of Organic Chemistry, 53, 2077-2077 (1988)
Chun-Wei Kuo et al.
Molecules (Basel, Switzerland), 17(11), 13662-13672 (2012-11-22)
Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.
Yvan Ecochard et al.
Molecules (Basel, Switzerland), 24(9) (2019-05-15)
Epoxy materials have attracted attention for many applications that require fireproof performance; however, the utilization of hazardous reagents brings about potential damage to human health. Eugenol and cardanol are renewable, harmless resources (according to ECHA) that allow the achievement of
Xiaoming Zhou et al.
Chemosphere, 235, 163-168 (2019-07-01)
Two novel phosphorus-containing copolyesters were synthesized by direct polycondensation reaction of phenyl dichlorophosphate, 1,4-succinic acid and 1,4-butanediol using stannous chloride (SnCl2) and 4-Methylbenzenesulfonic acid as catalyst, and its chemical structures were identified by 1H and 31P nuclear magnetic resonances (1H
R M Dawson et al.
Analytical biochemistry, 170(2), 451-455 (1988-05-01)
An improved method for assaying carbamylated acetylcholinesterase is described which has substantial benefits over current methods. Acetylcholinesterase was carbamylated with neostigmine and diluted extensively into buffer to allow decarbamylation to occur. At various times, phenyldichlorophosphate was added to the mixture
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