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Merck
CN

P6526

Sigma-Aldrich

Iron(III) pyrophosphate

soluble crystals

Synonym(s):

Diphosphoric acid iron(III) salt, Ferric pyrophosphate

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About This Item

Linear Formula:
Fe4(P2O7)3
CAS Number:
Molecular Weight:
745.21
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Form:
soluble crystals
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form

soluble crystals

Quality Level

composition

Iron content, 10.5-12.5%

reaction suitability

core: iron

concentration

10.5-12.5% (titration)

SMILES string

[Fe+3].[Fe+3].[Fe+3].[Fe+3].[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O

InChI

1S/4Fe.3H4O7P2/c;;;;3*1-8(2,3)7-9(4,5)6/h;;;;3*(H2,1,2,3)(H2,4,5,6)/q4*+3;;;/p-12

InChI key

CADNYOZXMIKYPR-UHFFFAOYSA-B

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General description

Ferric Phosphate is a tan or yellowish-white odorless powder. It is insoluble in water and soluble in mineral acids. It can be prepared by reacting sodium pyrophosphate with ferric citrate. It shows good bioaccesibility.

Application

Iron(III) pyrophosphate can be used:
  • As a cathode material for rechargeable batteries such as Na-ion batteries.
  • To fabricate a hybrid overlayer on the surface of metal oxides to boost photo electrochemical solar water splitting reaction.

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Laura Rossi et al.
Food chemistry, 151, 243-247 (2014-01-16)
Ferric pyrophosphate is a widely used material in the area of mineral fortification but its synthesis and properties in colloidal form are largely unknown. In this article, we report on the synthesis and characterisation of colloidal iron(III) pyrophosphate particles with
Perspective on Iron-Based Phosphate Cathode for Commercial Sodium-Ion Cells
Yajing Liu, et al
Small, 19, 2302972-2302972 (2023)
Maria Andersson et al.
The American journal of clinical nutrition, 88(5), 1378-1387 (2008-11-11)
Dual fortification of salt with iodine and iron could be a sustainable approach to combating iodine and iron deficiencies. We compared the efficacy of dual-fortified salt (DFS) made by using 2 proposed contrasting formulas-one fortifying with iron as micronized ground
Ruth Blanco-Rojo et al.
The British journal of nutrition, 105(11), 1652-1659 (2011-02-10)
Fe-deficiency anaemia is a worldwide health problem. We studied the influence of consuming an Fe-fortified fruit juice on Fe status in menstruating women. A randomised, double-blind, placebo-controlled study of 16 weeks of duration was performed. Subjects were randomised into two
Diego Moretti et al.
The American journal of clinical nutrition, 84(4), 822-829 (2006-10-07)
Iron fortification of rice could be an effective strategy for reducing iron deficiency anemia in South Asia. We aimed to determine whether extruded rice grains fortified with micronized ground ferric pyrophosphate (MGFP) would increase body iron stores in children. In

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