P9900
Perfluorodecalin
95%
Synonym(s):
Octadecafluorodecahydronaphthalene (cis+trans), Perflunafene, Perfluorodecahydronaphthalene (cis+trans)
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About This Item
Empirical Formula (Hill Notation):
C10F18
CAS Number:
Molecular Weight:
462.08
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-192-4
Beilstein/REAXYS Number:
2067113
MDL number:
Assay:
95%
InChI
1S/C10F18/c11-1-2(12,5(17,18)9(25,26)7(21,22)3(1,13)14)6(19,20)10(27,28)8(23,24)4(1,15)16
InChI key
UWEYRJFJVCLAGH-UHFFFAOYSA-N
SMILES string
FC1(F)C(F)(F)C(F)(F)C2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C2(F)C1(F)F
vapor density
17.5 (vs air)
assay
95%
refractive index
n20/D 1.3145 (lit.)
bp
142 °C (lit.)
mp
−10 °C (lit.)
density
1.908 g/mL at 25 °C (lit.)
Quality Level
Application
Perfluorodecalin is a fluorous solvent generally used as a primary component of the fluorous biphasic system (FBS) or the fluorous multiphasic system (FMS) in synthetic chemistry. It is also used as an additive to increase oxygen solubility in fermentation media.
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Three-component one-pot synthesis of pyrimidinone derivatives in fluorous media: Ytterbium bis (perfluorooctanesulfonyl) imide complex catalyzed Biginelli-type reaction.
Hong M and Cai C
Journal of Heterocyclic Chemistry, 46(6), 1430-1432 (2009)
Dilution-free analysis from picoliter droplets by nano-electrospray ionization mass spectrometry.
Ryan T Kelly et al.
Angewandte Chemie (International ed. in English), 48(37), 6832-6835 (2009-08-19)
Sc [N (SO2C8F17) 2] 3 catalyzed condensation of β-naphthol and aldehydes in fluorous solvent: One-pot synthesis of 14-substituted-14H-dibenzo [a, j] xanthenes.
Hong M and Cai C
Journal of Fluorine Chemistry, 130(10), 989-992 (2009)
Improvement of antibiotic production by increased oxygen solubility through the addition of perfluorodecalin.
Elibol M.
Journal of Chemical Technology and Biotechnology, 76(4), 418-422 (2001)
Convenient electrophilic fluorination of functionalized aryl and heteroaryl magnesium reagents.
Yamada S, et al.
Angewandte Chemie (International Edition in English), 122(12), 2261-2264 (2010)
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