S4007
Sodium iodate
≥99%
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About This Item
Linear Formula:
NaIO3
CAS Number:
Molecular Weight:
197.89
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.22
Assay:
≥99%
Quality Level
Assay
≥99%
density
4.28 g/mL at 25 °C (lit.)
SMILES string
[Na+].[O-]I(=O)=O
InChI
1S/HIO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
InChI key
WTCBONOLBHEDIL-UHFFFAOYSA-M
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Application
Sodium iodate (NaIO3) can be used as an oxidant in the following processes:
- NaIO3/neutral Al2O3 catalytic system is used to synthesize a variety of aromatic, aliphatic, and alicyclic disulfides via oxidation of the corresponding thiols.
- NaIO3/Na2SO3/HCl is used in the preparation of 2-amino-1-iodonaphthalene by iodination of 2-naphthylamine.
- NaIO3/acetic anhydride or glacial acetic acid is used in aromatic oxidative iodination reactions.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Ox. Sol. 2 - Skin Sens. 1
Storage Class Code
5.1B - Oxidizing hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Iodination of both deactivated and activated arenes with sodium periodate or sodium iodate as the oxidants
Lulinski P and Skulski L
Bulletin of the Chemical Society of Japan, 73(4), 951-956 (2000)
Simple Oxidation of Thiols with Sodium Iodate under Solid-Solution Biphasic Conditions
Hirano M, et al.
Journal of chemical research. Synopses, (12), 816-817 (1998)
Reaction of 2-Naphthylamine with Sodium Iodate/Sodium Sulfite: Synthesis of 2-Amino-1-iodonaphthalene
Taldone T, et al.
Synthetic Communications, 42(5), 635-638 (2012)
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