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Merck
CN

T30201

3,3′-Thiodipropionic acid

97%

Synonym(s):

Bis(2-carboxyethyl) sulfide

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About This Item

Linear Formula:
S(CH2CH2COOH)2
CAS Number:
Molecular Weight:
178.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-841-3
Beilstein/REAXYS Number:
1210299
MDL number:
Assay:
97%
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InChI key

ODJQKYXPKWQWNK-UHFFFAOYSA-N

InChI

1S/C6H10O4S/c7-5(8)1-3-11-4-2-6(9)10/h1-4H2,(H,7,8)(H,9,10)

SMILES string

OC(=O)CCSCCC(O)=O

assay

97%

mp

131-134 °C (lit.)

Quality Level

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Application

3,3′-Thiodipropionic acid is an organic disulfide that can be used as a ligand for the synthesis of cadminum and zinc coordination polymers with luminescent properties.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

262.4 °F - closed cup

flash_point_c

128 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Yasutaka Kamei et al.
Macromolecular bioscience, 7(3), 364-372 (2007-03-21)
To prepare sulfur-containing natural polymers effectively, several plant oils and 3,3'-thiodipropionic acid (TDP) have been used as carbon sources for the biosynthesis of copolymer poly[(3-hydroxybutyrate)-co-(3-mercaptopropionate)] [poly(3HB-co-3MP)] by a wild-type bacterium Cupriviadus necator H16. By using the plant oils, copolymer accumulation
L C McDonald et al.
Applied and environmental microbiology, 45(2), 360-365 (1983-02-01)
Escherichia coli LSUFS was injured either by freezing at -10 degrees C or by heating at 57 degrees C for 12 min. Surviving cells were recovered on nonselective tryptone-glucose extract agar and selective violet red bile agar supplemented with compounds
T Lütke-Eversloh et al.
Microbiology (Reading, England), 147(Pt 1), 11-19 (2001-02-13)
This is the first report on the biosynthesis of a hitherto unknown, sulfur-containing polyester and also the first report on a bacterial polymer containing sulfur in the backbone. The Gram-negative polyhydroxyalkanoate (PHA)-accumulating bacterium Ralstonia eutropha synthesized a copolymer of 3-hydroxybutyrate
Nadine Bruland et al.
The Journal of biological chemistry, 284(1), 660-672 (2008-11-13)
The thioether 3,3-thiodipropionic acid can be used as precursor substrate for biotechnological synthesis of 3-mercaptopropionic acid-containing polythioesters. Therefore, the hitherto unknown catabolism of this compound was elucidated to engineer novel and improved polythioester biosynthesis pathways in the future. Bacteria capable
Jan Hendrik Wübbeler et al.
Microbiology (Reading, England), 156(Pt 4), 1221-1233 (2009-12-05)
Application of the non-toxic 3,3'-thiodipropionic acid (TDP) and 3,3'-dithiodipropionic acid (DTDP) as precursors for the microbial production of polythioesters (PTEs), a class of biologically persistent biopolymers containing sulphur in the backbone, was successfully established previously. However, synthesis of PTEs containing

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