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T45004

Triallylamine

99%

Synonym(s):

TAA

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About This Item

Linear Formula:
(H2C=CHCH2)3N
CAS Number:
102-70-5
Molecular Weight:
137.22
NACRES:
NA.22
PubChem Substance ID:
24900211
UNSPSC Code:
12352100
EC Number:
203-048-2
MDL number:
MFCD00026093
Assay:
99%
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vapor density

4.73 (vs air)

Quality Level

200

vapor pressure

90 mmHg ( 80 °C)

assay

99%

refractive index

n20/D 1.451 (lit.)

bp

150-151 °C (lit.)

density

0.79 g/mL at 25 °C (lit.)

SMILES string

C=CCN(CC=C)CC=C

InChI

1S/C9H15N/c1-4-7-10(8-5-2)9-6-3/h4-6H,1-3,7-9H2

InChI key

VPYJNCGUESNPMV-UHFFFAOYSA-N

Application

  • Triallylamine (TAA) reacts with primary aromatic amines in the presence of a ruthenium catalyst to form 2-ethyl-3-methylquinolines.
  • TAA undergoes hydrozirconation followed by transmetalation with germanium tetrachloride to form 1-aza-5-germa-5-chlorobicyclo[3.3.3]undecane. This compound can react with Grignard or lithium reagents to form the corresponding 5-organo compounds.
  • The cycloaddition of TAA to fluorinated 1,3,4-oxadiazoles affords octahydro-2,7-methanofuro[3,2-c]pyridines.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

87.8 °F - closed cup

flash_point_c

31 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Certificates of Analysis (COA)

Lot/Batch Number
MKDB3830
MKCZ7207
MKCX6539
MKCX4170
MKCW3203

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Cycloaddition of fluorinated oxadiazoles with triallylamine.
Vasil?ev N V, et al.
Chemistry of Heterocyclic Compounds, 52(9), 750-752 (2016)
Marc Reinholdt et al.
Membranes, 2(3), 529-552 (2012-01-01)
In the highly competitive market of fuel cells, solid alkaline fuel cells using liquid fuel (such as cheap, non-toxic and non-valorized glycerol) and not requiring noble metal as catalyst seem quite promising. One of the main hurdles for emergence of
Ruthenium-catalyzed synthesis of 2-ethyl-3-methylquinolines from anilines and triallylamine.?
Cho C H, et al.
Tetrahedron Letters, 40(8), 1499-1500 (1999)
View All Related Papers

Global Trade Item Number

SKUGTIN
T45004-1L04061837330575
T45004-250ML04061837330582