T45004
Triallylamine
99%
Synonym(s):
TAA
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About This Item
Linear Formula:
(H2C=CHCH2)3N
CAS Number:
Molecular Weight:
137.22
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-048-2
MDL number:
Assay:
99%
InChI key
VPYJNCGUESNPMV-UHFFFAOYSA-N
InChI
1S/C9H15N/c1-4-7-10(8-5-2)9-6-3/h4-6H,1-3,7-9H2
SMILES string
C=CCN(CC=C)CC=C
vapor density
4.73 (vs air)
vapor pressure
90 mmHg ( 80 °C)
assay
99%
refractive index
n20/D 1.451 (lit.)
bp
150-151 °C (lit.)
density
0.79 g/mL at 25 °C (lit.)
Quality Level
Related Categories
Application
- Triallylamine (TAA) reacts with primary aromatic amines in the presence of a ruthenium catalyst to form 2-ethyl-3-methylquinolines.
- TAA undergoes hydrozirconation followed by transmetalation with germanium tetrachloride to form 1-aza-5-germa-5-chlorobicyclo[3.3.3]undecane. This compound can react with Grignard or lithium reagents to form the corresponding 5-organo compounds.
- The cycloaddition of TAA to fluorinated 1,3,4-oxadiazoles affords octahydro-2,7-methanofuro[3,2-c]pyridines.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
87.8 °F - closed cup
flash_point_c
31 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Ruthenium-catalyzed synthesis of 2-ethyl-3-methylquinolines from anilines and triallylamine.?
Cho C H, et al.
Tetrahedron Letters, 40(8), 1499-1500 (1999)
Cycloaddition of fluorinated oxadiazoles with triallylamine.
Vasil?ev N V, et al.
Chemistry of Heterocyclic Compounds, 52(9), 750-752 (2016)
Marc Reinholdt et al.
Membranes, 2(3), 529-552 (2012-01-01)
In the highly competitive market of fuel cells, solid alkaline fuel cells using liquid fuel (such as cheap, non-toxic and non-valorized glycerol) and not requiring noble metal as catalyst seem quite promising. One of the main hurdles for emergence of
Palladium-catalyzed reaction of 1-aza-5-germa-5-organobicyclo [3.3. 3] undecane with aryl bromide.
Kosugi M, et al.
Journal of Organometallic Chemistry, 508(1-2), 255-257 (1996)
E D Thompson et al.
Environmental and molecular mutagenesis, 18(3), 184-199 (1991-01-01)
Three cross-linked polyacrylate polymers containing either methylenebis-acrylamide (MBA), trimethylolpropane triacrylate (TMPTA), or triallylamine (TAA) cross-linkers were tested for genotoxicity with the Salmonella mammalian microsome assay, the L5178Y mouse lymphoma TK +/- assay, the unscheduled DNA synthesis assay in primary cultures
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