T58009
Tridecylamine
98%
Synonym(s):
1-Aminotridecane
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About This Item
Linear Formula:
CH3(CH2)12NH2
CAS Number:
Molecular Weight:
199.38
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-694-0
Beilstein/REAXYS Number:
1739990
MDL number:
Assay:
98%
InChI key
ABVVEAHYODGCLZ-UHFFFAOYSA-N
InChI
1S/C13H29N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14/h2-14H2,1H3
SMILES string
CCCCCCCCCCCCCN
assay
98%
bp
265 °C (lit.)
mp
30-32 °C (lit.)
Quality Level
Related Categories
Application
Tridecylamine can undergo:
- Dehydrogenation to nitriles catalyzed by ruthenium complex.
- Aerobic oxidation to carbonyl compounds catalyzed by vitamin C and Cu complex.
Tridecylamine is generally used in introducing C13 chain to the substrate. Some of the application are:
- Synthesis of alkylated 1,2,4-triazoles as bridging ligand in the preparation of polymeric 1-dimensional chains of iron(II) species.
- Synthesis of amphiphiles such as N-tridecyl-β-hydroxypropionic acid amide (THPA) and N-(β-hydroxyethyl)tridecanoic acid amide (HETA).
- As a ligand in the preparation of palladium-based catalyst, [PdCl2(TDA)2].
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Spin-transition behaviour in chains of Fe II bridged by 4-substituted 1, 2, 4-triazoles carrying alkyl tails,.
Roubeau O, et al.
New. J. Chem., 25(1), 144-150 (2001)
Catalytic investigation of PdCl2 (TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction.
Mastalir A, et al.
Reaction Kinetics, Mechanisms and Catalysis, 113(1), 61-68 (2014)
Effect of the exchange of substituent position in an amide amphiphile on the monolayer characteristics.
Vollhardt D and Wagner R
The Journal of Physical Chemistry B, 110(30), 14881-14889 (2006)
1-Heptyne semihydrogenation catalized by palladium or rhodium complexes: Influence of: metal atom, ligands and the homo/heterogeneous condition.
Quiroga M E, et al.
Applied Catalysis A: General, 326(2), 121-129 (2007)
Copper/ascorbic acid dyad as a catalytic system for selective aerobic oxidation of amines
Srogl J and Voltrova S
Organic Letters, 11(4), 843-845 (2009)
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