T61204
Triethyl phosphite
98%
Synonym(s):
P(EtO)3, P(OEt)3
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About This Item
Linear Formula:
(C2H5O)3P
CAS Number:
Molecular Weight:
166.16
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-552-5
Beilstein/REAXYS Number:
956578
MDL number:
Quality Level
assay
98%
reaction suitability
reaction type: Reductions
impurities
≤1% triethyl phosphate and diethyl phosphite
refractive index
n20/D 1.413 (lit.)
bp
156 °C (lit.)
density
0.969 g/mL at 25 °C (lit.)
SMILES string
CCOP(OCC)OCC
InChI
1S/C6H15O3P/c1-4-7-10(8-5-2)9-6-3/h4-6H2,1-3H3
InChI key
BDZBKCUKTQZUTL-UHFFFAOYSA-N
Application
Used as a reducing agent; can react with electrophiles to form phosphonates or phosphates; forms a stable complex with copper(I) iodide.
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 3 - Skin Sens. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
129.2 °F - closed cup
flash_point_c
54 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
监管及禁止进口产品
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Related Content
Phosphine Ligand Application Guide
Kyriacos Agapiou et al.
Journal of the American Chemical Society, 126(14), 4528-4529 (2004-04-09)
Exposure of enone substrates 1a-18a, which possess appendant ketone, ester, and nitrile moieties, to Et2Zn in the presence of catalytic Cu(OTf)2/P(OEt)3 provides the cyclized products in good to excellent yields and diastereoselectivities. These results represent the first use of ketones
Stowell, J. K.; Widlanski, T. S. et al.
Tetrahedron Letters, 36, 1825-1825 (1995)
Gabriele Albertin et al.
Dalton transactions (Cambridge, England : 2003), 44(35), 15470-15480 (2015-08-04)
Diazoalkane complexes [Ru(Tp)(N2CAr1Ar2)(PPh3)L]BPh4 ( and ) [Tp = tris(pyrazolyl)borate; L = P(OMe)3, P(OEt)3; Ar1 = Ar2 = Ph; Ar1 = Ph, Ar2 = p-tolyl; Ar1Ar2 = C12H8] were prepared by allowing chloro-compounds RuCl(Tp)(PPh3)L to react with diazoalkane in the presence
Global Trade Item Number
| SKU | GTIN |
|---|---|
| T61204-5ML | 04061837358340 |
| T61204-100ML | 04061837358319 |
| T61204-500ML | 04061837358333 |
| T61204-4L | 04061837358326 |