T80500
Trimethylsulfoxonium iodide
98%
Synonym(s):
Iodotrimethyloxosulfur, S,S,S-Trimethylsulfoxonium iodide, Trimethyl(oxo)-λ6-sulfanylium iodide, Trimethyloxosulfonium iodide, Trimethyloxosulphonium iodide, Trimethylsulfoxonium iodide (7CI)
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About This Item
Linear Formula:
(CH3)3S(I)O
CAS Number:
Molecular Weight:
220.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-204-2
Beilstein/REAXYS Number:
3595854
MDL number:
Assay:
98%
Quality Level
assay
98%
mp
208-212 °C (dec.) (lit.)
SMILES string
[I-].C[S+](C)(C)=O
InChI
1S/C3H9OS.HI/c1-5(2,3)4;/h1-3H3;1H/q+1;/p-1
InChI key
BPLKQGGAXWRFOE-UHFFFAOYSA-M
Application
Treatment with strong base yields the ylide which adds to the carbonyl group of ketones and aldehydes to give epoxides. Also adds preferentially to the double bond of α,β-unsaturated esters to give cyclopropyl esters.
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Tetrahedron, 48, 5089-5089 (1992)
Tetrahedron, 49, 5067-5067 (1993)
W T Ashton et al.
Journal of medicinal chemistry, 35(11), 2103-2112 (1992-05-29)
A series of transition-state analogues having heterocyclythio C-termini has been synthesized and evaluated for inhibition of human renin. Addition of mercaptoheterocycles to a chiral Boc-amino epoxide intermediate led, after several steps, to the target [(2R,3S)-3-(BocPheHis-amino)-4-cyclohexyl-2-hydroxy-1-butyl]thio derivatives. Oxidation of the thioether
Global Trade Item Number
| SKU | GTIN |
|---|---|
| T80500-500G | 04061833554197 |
| T80500-100G | 04061837378850 |
| T80500-25G | 04061833554180 |