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Merck
CN

05-4610

Chromium(VI) oxide

SAJ first grade, ≥95.0%

Synonym(s):

Chromic anhydride

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About This Item

Empirical Formula (Hill Notation):
CrO3
CAS Number:
Molecular Weight:
99.99
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
215-607-8
MDL number:
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grade

SAJ first grade

assay

≥95.0%

availability

available only in Japan

mp

196 °C (dec.) (lit.)

SMILES string

O=[Cr](=O)=O

InChI

1S/Cr.3O

InChI key

WGLPBDUCMAPZCE-UHFFFAOYSA-N



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signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 1B - Ox. Sol. 1 - Repr. 2 - Resp. Sens. 1 - Skin Corr. 1A - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges

Regulatory Information

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M C García-Rodríguez et al.
Mutation research, 496(1-2), 145-151 (2001-09-12)
The effect of chlorophyllin on micronucleated polychromatic erythrocytes (MN-PCE) induction by chromium trioxide (CrO(3)) exposure in peripheral blood of mice was studied. Animals were treated with a single intraperitoneal dose of chlorophyllin (CHL) (20mg/kg), CrO(3) (20mg/kg), and CHL (20mg/kg) 4h
Seongmin Lee et al.
Organic letters, 11(1), 5-8 (2008-12-06)
The C14,15-dihydro-C22,25-epi north unit of cephalostatin 1 has been synthesized in 11 operations from commercially available hecogenin acetate via multiple reductions and oxidations. The key transformations include (i) Cr(VI)-catalyzed E-ring opening, (ii) C17 hydroxylation, and (iii) a base-triggered cyclization cascade.
S Kondo et al.
European journal of biochemistry, 200(3), 689-698 (1991-09-15)
The chemical structure of the saccharide portion of Vibrio parahaemolyticus serotype 012 lipopolysaccharide was studied. Using chemical degradation and modification, as well as methylation analysis in combination with GLC-MS, laser-desorption mass spectrometry and 1H-NMR and 13C-NMR spectroscopy, the carbohydrate backbone