07-3870
Diisopropylamine
SAJ first grade, ≥98.0%
Synonym(s):
DIPA
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About This Item
Linear Formula:
(CH3)2CHNHCH(CH3)2
CAS Number:
Molecular Weight:
101.19
EC Number:
203-558-5
UNSPSC Code:
12352116
PubChem Substance ID:
Beilstein/REAXYS Number:
605284
MDL number:
grade
SAJ first grade
vapor density
3.5 (vs air)
vapor pressure
50 mmHg ( 20 °C)
assay
≥98.0%
form
liquid
autoignition temp.
599 °F
expl. lim.
8.5 %
availability
available only in Japan
refractive index
n20/D 1.392 (lit.)
bp
84 °C (lit.)
mp
−61 °C (lit.)
density
0.722 g/mL at 25 °C (lit.)
SMILES string
CC(C)NC(C)C
InChI
1S/C6H15N/c1-5(2)7-6(3)4/h5-7H,1-4H3
InChI key
UAOMVDZJSHZZME-UHFFFAOYSA-N
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signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
7.8 °F - closed cup
flash_point_c
-13.45 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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Songping Liao et al.
Journal of the American Chemical Society, 125(49), 15114-15127 (2003-12-05)
Lithium diisopropylamide-mediated lithiations of N-alkyl ketimines derived from cyclohexanones reveal that simple substitutions on the N-alkyl side chain and the 2-position of the cyclohexyl moiety afford a 60,000-fold range of rates. Detailed rate studies implicate monosolvated monomers at the rate-limiting
Decoupling deprotonation from metalation: Thia-Fries rearrangement.
Alan M Dyke et al.
Angewandte Chemie (International ed. in English), 47(27), 5067-5070 (2008-05-28)
Koichi Mikami et al.
Chemical record (New York, N.Y.), 6(1), 1-11 (2006-02-14)
The difficulty as well as the significance of the direct generation of metal enolates of alpha-CF(3) ketones cannot be easily understood by chemists unfamiliar with F. In sharp contrast to the sunny side of non-F, hydrocarbon chemistry, F chemistry has