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Merck
CN

28-6160

Sulfuryl chloride

SAJ first grade, ≥90.0%

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About This Item

Linear Formula:
SO2Cl2
CAS Number:
Molecular Weight:
134.97
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
232-245-6
MDL number:
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InChI key

YBBRCQOCSYXUOC-UHFFFAOYSA-N

InChI

1S/Cl2O2S/c1-5(2,3)4

SMILES string

ClS(Cl)(=O)=O

grade

SAJ first grade

vapor density

4.7 (vs air)

vapor pressure

100 mmHg ( 17.8 °C), 105 mmHg ( 20 °C)

assay

≥90.0%

form

liquid

availability

available only in Japan

bp

68-70 °C (lit.)

mp

−54 °C (lit.)

density

1.665 g/mL at 20 °C (lit.)

pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Eye Dam. 1 - Skin Corr. 1C - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Qian Wu et al.
Chemical communications (Cambridge, England), 47(32), 9188-9190 (2011-07-14)
A new, efficient protocol for the synthesis of di(hetero)aryl sulfides is described. Cheap and easily available arylsulfonyl chlorides as a sulfur source reductively couple with electron-rich (hetero)arenes (e.g., indolizines, indoles, electron-rich benzenes, etc.) in the presence of triphenylphosphine to afford
Philippe Hermange et al.
Organic letters, 11(18), 4044-4047 (2009-08-15)
Reaction of an isoquinoline, a silyloxyfuran, and an acyl or sulfonyl chloride provides easy access to a wide variety of isoquinolinobutyrolactones with excellent yields and diastereoselectivites (R*,R* isomer), even in the case of formation of quaternary centers (i.e., R(3) or
Xiaoming Zeng et al.
Journal of the American Chemical Society, 133(44), 17638-17640 (2011-10-13)
A variety of polysubstituted 1H-indenes can be prepared through the copper-catalyzed arylative cyclization of simple arylalkynes with commercially available aromatic sulfonyl chlorides that function as an aryl group donor. The reaction tolerates a broad range of functional groups, including bromide
Ourida Saidi et al.
Journal of the American Chemical Society, 133(48), 19298-19301 (2011-11-04)
A selective catalytic meta sulfonation of 2-phenylpyridines was found to occur in the presence of (arene)ruthenium(II) complexes upon reaction with sulfonyl chlorides. The 2-pyridyl group facilitates the formation of a stable Ru-C(aryl) σ bond that induces a strong para-directing effect.
Tandem cyclizations of 1,6-enynes with arylsulfonyl chlorides by using visible-light photoredox catalysis.
Guo-Bo Deng et al.
Angewandte Chemie (International ed. in English), 52(5), 1535-1538 (2013-01-05)

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