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About This Item
Linear Formula:
CH3COCH3
CAS Number:
Molecular Weight:
58.08
EC Number:
200-662-2
UNSPSC Code:
12352115
PubChem Substance ID:
Beilstein/REAXYS Number:
635680
MDL number:
NACRES:
NA.21
InChI key
CSCPPACGZOOCGX-UHFFFAOYSA-N
InChI
1S/C3H6O/c1-3(2)4/h1-2H3
SMILES string
CC(C)=O
vapor pressure
184 mmHg ( 20 °C), 184 mmHg
grade
purum
assay
≥99.0% (GC)
form
liquid
expl. lim.
13.2 %, 8 % (lit.)
impurities
≤1% water
mp
-94 °C (lit.), −94 °C (lit.)
density
0.791 g/mL at 25 °C (lit.)
format
neat
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General description
Photocatalytic activity of mixtures of TiO2 (P25) with rare earth oxides for the oxidation of acetone has been reported. The vapor-phase Aldol condensation of acetone over MgO promoted with alkali (Li, Na, K and Cs) or alkaline earth (Ca, Sr and Ba) metal ions has been studied. Acetone undergoes Aldol condensation in the presence of catalysts Mg-Al layered double hydroxides (LDH) and Cl- and/or CO32- as compensating anions to afford diacetone alcohol and mesityl oxide. Enantioselective Aldol condensation of acetone with several isatins has been described.
Application
Acetone may be employed in the following studies:
- As organic solvent to investigate the zeta potential of TiO2 and Al2O3 powders.
- Synthesis of poly(ortho esters) (POE), biodegradable carriers for drug delivery devices.
- Spectrophotometric determination of ester groups in lipids.
Acetone′s luminesence intensity is dependent upon the solution components . The absorption of UV light by acetone, results in its photolysis and the production of radials .
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
1.4 °F - closed cup
flash_point_c
-17.0 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
Regulatory Information
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A Merkli et al.
Journal of biomaterials science. Polymer edition, 4(5), 505-516 (1993-01-01)
Since the late 1970s, three families of poly(ortho esters) (POE) were synthesized to provide bioerodible carriers for drug delivery devices. The most recent POE is a semi-solid polymer with a viscous behavior at room temperature. Polymer synthesis by a transesterification
Location of the shear plane in the electric double layer in an organic medium.
Siffert B, et al.
Journal of Colloid and Interface Science, 163(2), 327-333 (1992)
A simplified spectrophotometric determination of ester groups in lipids.
F SNYDER et al.
Biochimica et biophysica acta, 34, 244-245 (1959-07-01)
Base catalysis for the synthesis of α,β-unsaturated ketones from the vapor-phase aldol condensation of acetone.
Di Cosimo JI, et al.
Applied Catalysis A: General, 137(1), 149-166 (1996)
Gianluigi Luppi et al.
The Journal of organic chemistry, 70(18), 7418-7421 (2005-08-27)
[reaction: see text] The aldol condensation of acetone with several isatins is described. The desired compound was obtained in quantitative yield and with good enantioselectivities up to 77%. The best results were obtained with 10 mol % H-D-Pro-L-beta3-hPhg-OBn as a
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