02115
Copper(II) bromide
≥99%
Synonym(s):
Cupric bromide
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About This Item
Linear Formula:
CuBr2
CAS Number:
Molecular Weight:
223.35
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
232-167-2
MDL number:
assay
≥99%
impurities
≤0.3% subst. not precipitated by H2S (as SO4)
mp
498 °C (lit.)
density
4.77 g/mL at 25 °C (lit.)
anion traces
sulfate (SO42-): ≤5000 mg/kg
cation traces
As: ≤50 mg/kg, Fe: ≤500 mg/kg
SMILES string
Br[Cu]Br
InChI
1S/2BrH.Cu/h2*1H;/q;;+2/p-2
InChI key
QTMDXZNDVAMKGV-UHFFFAOYSA-L
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Shengqing Ye et al.
Chemical communications (Cambridge, England), (36)(36), 5406-5408 (2009-09-03)
Palladium-catalyzed tandem reactions of 2-alkenylphenyl-acetylenes with CuCl2 or CuBr2 afforded 3-chloro- or 3-bromo-1-methyleneindenes in good yields; these compounds could be further elaborated via palladium-catalyzed coupling reactions.
Robin B Bedford et al.
Dalton transactions (Cambridge, England : 2003), 39(43), 10464-10472 (2010-10-12)
The solvent-free, palladium-catalysed reaction of anilides with CuCl(2) in the presence or absence of copper acetate yields ortho-chlorinated anilides in good to excellent yields, even on a large scale (100 mmol). By contrast, the equivalent reactions with copper bromide, either
Yi-Si Feng et al.
Organic letters, 15(7), 1472-1475 (2013-03-12)
Cu-catalyzed decarboxylative alkynylation of quaternary α-cyano acetate salts with alkynyl bromides and alkynyl chlorides is described. This new reaction can be used for preparing functionalized butynenitrile derivatives.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| I3502-10G | 04061833856178 |
| I3502-50G | 04061833856185 |