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Merck
CN

02315

Dimethyl L-malate

puriss., ≥99.0% (sum of enantiomers, GC)

Synonym(s):

Dimethyl (S)-2-hydroxysuccinate

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About This Item

Empirical Formula (Hill Notation):
C6H10O5
CAS Number:
Molecular Weight:
162.14
PubChem Substance ID:
UNSPSC Code:
12352000
EC Number:
432-310-0
MDL number:
Beilstein/REAXYS Number:
1724363
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grade

puriss.

assay

≥99.0% (sum of enantiomers, GC)

optical activity

[α]20/D −6.6±0.5°, neat

refractive index

n20/D 1.441

bp

104-108 °C/1 mmHg (lit.)

density

1.232 g/mL at 20 °C (lit.)

storage temp.

2-8°C

SMILES string

COC(=O)C[C@H](O)C(=O)OC

Other Notes

Starting material used for the synthesis of many chiral building blocks; Selective reduction of the 1-ester group with BH3.SMe2; Diastereoselective alkylation of C-3


signalword

Danger

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - Skin Sens. 1

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

131.0 °F

flash_point_c

55 °C

ppe

Eyeshields, Gloves

Regulatory Information

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S. Saito
Chemistry Letters (Jpn), 1389-1389 (1984)
D. Wasmuth et al.
Helvetica Chimica Acta, 65, 344-344 (1982)
D. Seebach et al.
Organic Syntheses, 63, 109-109 (1985)



Global Trade Item Number

SKUGTIN
B64202-25G04061833434789