02610
Ethyl dimethylphosphonoacetate
technical, ≥90% (GC)
Synonym(s):
Ethoxycarbonylmethylphosphonic acid dimethylester, Phosphonoacetic acid P,P-dimethyl ethylester
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About This Item
Linear Formula:
(CH3O)2P(O)CH2COOC2H5
CAS Number:
Molecular Weight:
196.14
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-222-6
Beilstein/REAXYS Number:
1777603
MDL number:
InChI key
HUNISAHOCCASGM-UHFFFAOYSA-N
InChI
1S/C6H13O5P/c1-4-11-6(7)5-12(8,9-2)10-3/h4-5H2,1-3H3
SMILES string
CCOC(=O)CP(=O)(OC)OC
grade
technical
assay
≥90% (GC)
form
liquid
reaction suitability
reaction type: C-C Bond Formation
Quality Level
bp
134 °C/10 mmHg (lit.)
density
1.188 g/mL at 25 °C (lit.)
Application
Reactant for synthesis of:
Reactant for:
- Non-nucleoside inhibitors of HCV polymerase NS5B
- Neuropeptide Y1 receptor antagonists
- Alkenylcarboxylates from Horner-Wadsworth-Emmons reactions
Reactant for:
- Enantioselective transfer hydrogenation for preparation of the C7-C14 fragment of ulapualide A
- Intramolecular Michael reactions
- Olefination of peptidyl aldehydes with stabilized ylides
Other Notes
Horner-Wittig reagent
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
210.2 °F - closed cup
flash_point_c
99 °C - closed cup
ppe
Eyeshields, Gloves
Regulatory Information
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Hans M Larsson et al.
PloS one, 9(2), e90006-e90006 (2014-03-04)
Although urothelial progenitor-like cells have been described in the human urinary tract, the existence of stem cells remains to be proven. Using a culture system that favors clonogenic epithelial cell growth, we evaluated and characterized clonal human urothelial cells. We
Marie-Anaïs Locquet et al.
Cells, 10(2) (2021-03-07)
Chordomas are rare, slow-growing tumors of the axial skeleton. These tumors are locally aggressive and refractory to conventional therapies. Radical surgery and radiation remain the first-line treatments. Despite these aggressive treatments, chordomas often recur and second-line treatment options are limited.
W.S. Wadsworth
Org. React., 25, 73-73 (1977)
Marjaana Rantala et al.
Bio-protocol, 8(13), e2899-e2899 (2018-07-05)
The hierarchical composition and interactions of the labile thylakoid protein complexes can be assessed by sequential 2D-native gel-electrophoresis system. Mild non-ionic detergent digitonin is used to solubilize labile protein super-and megacomplexes, which are then separated with first-dimension blue native polyacrylamide
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