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Merck
CN

03560

Ethylenediamine

purum, ≥99.0% (GC)

Synonym(s):

1,2-Diaminoethane

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About This Item

Linear Formula:
NH2CH2CH2NH2
CAS Number:
Molecular Weight:
60.10
EC Number:
203-468-6
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
605263
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InChI

1S/C2H8N2/c3-1-2-4/h1-4H2

InChI key

PIICEJLVQHRZGT-UHFFFAOYSA-N

SMILES string

NCCN

vapor density

2.07 (vs air)

vapor pressure

10 mmHg ( 20 °C)

grade

purum

assay

≥99.0% (GC)

autoignition temp.

716 °F

expl. lim.

16 %

impurities

≤1% water

refractive index

n20/D 1.4565 (lit.), n20/D 1.457

bp

118 °C (lit.)

mp

8.5 °C (lit.)

density

0.899 g/mL at 25 °C (lit.)

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Application

Ethylenediamine solution was used in the synthesis of ultra-small CdSe quantum dots. It may be used as solvent in the preparation of ZnS and ZnSe precursors (ZnS·0.5en and ZnSe·0.5en, en = ethylenediamine), via solvothermal process. It may be employed for the synthesis of inulin based polycation (Inu-EDA).

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Resp. Sens. 1B - Skin Corr. 1B - Skin Sens. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

100.4 °F - closed cup

flash_point_c

38 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Mild synthesis of ultra-small CdSe quantum dots in ethylenediamine solution.
Yoon J-H, et al.
Materials Letters, 59(11), 1430-1433 (2005)
Absorption of carbon dioxide into aqueous solutions of ethylenediamine: Effect of interfacial turbulence.
Sada E, et al.
Chemical Engineering Journal, 13(3), 213-217 (1977)
Mariano Licciardi et al.
Pharmaceutical research, 32(11), 3674-3687 (2015-06-19)
An inulin based polycation (Inu-EDA) has been synthesized by the grafting of ethylenediamine molecules onto inulin backbone. The obtained inulin copolymer has been though to coat SPIONs (IC-SPIONs) and obtain stable magnetoplexes by complexation of IC-SPIONs with a model duplexed
Zhao-Xiang Deng et al.
Inorganic chemistry, 41(4), 869-873 (2002-02-19)
ZnS and ZnSe precursors (ZnS x 0.5en and ZnSe x 0.5en, en = ethylenediamine) were prepared via a solvothermal process using ethylenediamine as solvent. Phase-pure hexagonal wurtzite ZnS and ZnSe products were obtained by annealing the precursors in argon stream
Maria V Babak et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(13), 4308-4318 (2013-01-24)
With the aim of systematically studying fundamental structure-activity relationships as a basis for the development of Ru(II) arene complexes (arene = p-cymene or biphenyl) bearing mono-, bi-, or tridentate am(m)ine ligands as anticancer agents, a series of ammine, ethylenediamine, and

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