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Merck
CN

04114

Phosphorous acid

≥98.5%

Synonym(s):

Phosphonic acid

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About This Item

Empirical Formula (Hill Notation):
H3O3P
CAS Number:
Molecular Weight:
82.00
UNSPSC Code:
12352106
PubChem Substance ID:
EC Number:
237-066-7
MDL number:
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assay

≥98.5%

impurities

≤0.002% heavy metals (as Pb), ≤1% phosphoric acid (H3PO4)

density

1.651 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤10 mg/kg

cation traces

Fe: ≤5 mg/kg

SMILES string

[H]P(O)(O)=O

InChI

1S/H3O3P/c1-4(2)3/h4H,(H2,1,2,3)

InChI key

ABLZXFCXXLZCGV-UHFFFAOYSA-N

Application

Phosphorous acid (H3PO3) may be used for the synthesis of α-aminomethylphosphonic acids, via Mannich type reaction.


pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Rickard DA.
Journal of Plant Nutrition, 22(36), 3537-3540 (1981)
Anodic oxidation mechanism of hypophosphorous and phosphorous acid on palladium.
Trasatti S and Alberti A.
Journal of Electroanalytical Chemistry, 12(3), 236-249 (1966)
Ping Yin et al.
Bioresource technology, 110, 258-263 (2012-02-22)
Esterification of oleic acid with ethanol catalyzed by organophosphonic acid-functionalized silica SG-T-P was optimized using response surface methodology (RSM). The interactive effect of catalyst to FFA weight ratio and molar ratio of alcohol to acid were more significant than that