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Merck
CN

06160

Aluminum acetylacetonate

purum, crystallized, ≥95.0% (KT)

Synonym(s):

Al(acac)3, Aluminum 2,4-pentanedionate

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About This Item

Linear Formula:
Al(C5H7O2)3
CAS Number:
13963-57-0
Molecular Weight:
324.31
EC Number:
237-741-6
UNSPSC Code:
12352300
PubChem Substance ID:
329748215
Beilstein/REAXYS Number:
4157942
MDL number:
MFCD00000013

Key Documents

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InChI key

KILURZWTCGSYRE-LNTINUHCSA-K

InChI

1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

SMILES string

CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

grade

purum

assay

≥95.0% (KT)

form

solid

quality

crystallized

reaction suitability

core: aluminum, reagent type: catalyst

bp

315 °C (lit.)

mp

190-193 °C (lit.), 192-195 °C

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pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

244.4 °F

flash_point_c

118 °C

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Regulatory Information

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L Fontana et al.
Biological trace element research, 31(2), 183-191 (1991-11-01)
The toxicity of i.v. injected hydrophilic aluminum complex tris(maltolate)aluminum(III) was studied in New Zealand white rabbits for a period of time ranging from 5 to 63 wk. Animals were injected 3-5 times a week with 1 mL of 7.5 mM
P Zatta et al.
Toxicology letters, 45(1), 15-21 (1989-01-01)
Tris acetylacetonate aluminium(III) (Al(acac)3), dissolved in water, is effective in producing osmotic fragility in suspended erythrocytes in the concentration range of 0.034-0.34 mmol/l. Water solutions of Tris maltolate aluminium(III) (Al(malt)3) and aluminium lactate (Al(lac)3) are also effective but the dose-response
G G Bombi et al.
Environmental health perspectives, 89, 217-223 (1990-11-01)
Aluminum lactate [Al(lact)3] (hydrophilic, hydrolytically unstable) and aluminum acetylacetonate [Al(acae)3] (lipophilic, hydrolytically stable) were tested as potential toxicants to rabbits upon IV administration both as aqueous solutions and as liposome suspensions. Both chemicals behaved as cardiotoxic agents when administered as
P Zatta et al.
Journal of inorganic biochemistry, 65(2), 109-114 (1997-02-01)
The action of aluminum [Al(III)] as Al(acac)3 on erythrocytes causes biophysical effects such as osmotic fragility and echino-acanthocytes formation. In this paper, we present these effects in terms of variation of membrane fluidity, together with findings regarding conformational modifications of
John W Logan et al.
Solid state nuclear magnetic resonance, 22(2-3), 97-109 (2002-12-10)
Additional experimental evidence of rotary resonance effects for multiple-quantum coherence conversion in a spin-5/2 system is presented. Two-dimensional plots of the relative efficiency of MQ excitation and conversion are given as a function of radio frequency (rf) amplitude and pulse
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