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Merck
CN

06849

Cap B (1-methylimidazole 16% in THF)

filtered through a 1μm filter

Synonym(s):

1-Methylimidazole solution

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About This Item

Empirical Formula (Hill Notation):
C4H6N2
CAS Number:
Molecular Weight:
82.10
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
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InChI

1S/C4H6N2/c1-6-3-2-5-4-6/h2-4H,1H3

SMILES string

Cn1ccnc1

InChI key

MCTWTZJPVLRJOU-UHFFFAOYSA-N

quality

filtered through a 1μm filter

impurities

<0.01% water

Application

1-Methylimidazole has been used in a study to elaborate on the use of differential scanning calorimetry as a new indirect method for determination of vaporization enthalpies. 1-Methylimidazole has also been used in a study that analyzed the base content in in-service oils by Fourier Transform Infrared Spectroscopy.

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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

1.4 °F

flash_point_c

-17 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Sergey P Verevkin et al.
The journal of physical chemistry. B, 116(14), 4276-4285 (2012-03-23)
Differential scanning calorimetry (DSC) has been used to measure enthalpies of synthesis reactions of the 1-alkyl-3-methylimidazolium bromide [C(n)mim][Br] ionic liquids from 1-methylimidazole and n-alkyl bromides (with n = 4, 5, 6, 7, and 8). The optimal experimental conditions have been
Sadia Ehsan et al.
Journal of laboratory automation, 17(3), 201-210 (2012-02-24)
An automated FTIR method for the determination of the base content (BC(pKa)) of oils at rates of > 120 samples/h has been developed. The method uses a 5% solution of trifluoroacetic acid in 1-propanol (TFA/P) added to heptane-diluted oil to
Malachy McCann et al.
Dalton transactions (Cambridge, England : 2003), 41(21), 6516-6527 (2012-04-06)
[Ag(2)(9-aca)(2)] (1) (9-acaH = 9-anthracenecarboxylic acid) reacts with a series of imidazoles to give [Ag(imidH)(2.3)(CH(3)CN)(0.7)](9-aca) (3), [Ag(6)(imidH)(4)(9-aca)(6)(MeOH)(2)] (4), {[Ag(1-Me-imid)(2)](2)[Ag(4)(9-aca)(6)]} (5), {[Ag(1-Bu-imid)(2)](2)[Ag(4)(9-aca)(6)]} (6) and [Ag(apim)](9-aca)·H(2)O (7) (imidH = imidazole; 1-Me-imid = 1-methylimidazole; 1-Bu-imid = 1-butylimidazole; apim = 1-(3-aminopropyl)imidazole). The mononuclear complex
Pengfei Zhang et al.
Journal of chromatography. A, 1218(22), 3459-3465 (2011-04-19)
The development of mixed-mode stationary phase to achieve multiple separation capabilities in one column is very important for high performance liquid chromatography. In this paper, a new specific stationary phase based on grafting N-methylimidazolium to a monolithic silica column was
Zhan-Yong Wang et al.
The Journal of organic chemistry, 77(15), 6608-6614 (2012-07-19)
A well-defined NHC-Pd(II)-Im complex 1 was found to be an effective catalyst for the Suzuki-Miyaura coupling of aryl sulfonates including tosylates and phenylsulfonates with arylboronic acids, giving the desired coupling products in good to high yields. Acceptable yields can also

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