08416
(S)-4-Benzyloxazolidine-2-thione
≥97.0%
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About This Item
Empirical Formula (Hill Notation):
C10H11NOS
CAS Number:
Molecular Weight:
193.27
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Quality Level
assay
≥97.0%
optical purity
enantiomeric excess: ≥98.0% (HPLC)
mp
63-67 °C
functional group
phenyl
SMILES string
S=C1N[C@H](CO1)Cc2ccccc2
InChI
1S/C10H11NOS/c13-10-11-9(7-12-10)6-8-4-2-1-3-5-8/h1-5,9H,6-7H2,(H,11,13)/t9-/m0/s1
InChI key
WJSUXYCBZFLXIK-VIFPVBQESA-N
Application
A highly selective and efficient chiral auxiliary which can be directly reduced to its corresponding aldehyde and the chiral auxiliary by reductive cleavage with diisobutylaluminum hydride.
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Velazquez. F.; Olivo, H. F.
Current Organic Chemistry, 6, 303-303 (2002)
M T Crimmins et al.
Organic letters, 2(6), 775-777 (2001-02-07)
[formula: see text] Asymmetric aldol additions using chlorotitanium enolates of thiazolidinethione propionates proceed with high diastereoselectivity for the "Evans" or "non-Evans" syn product depending on the nature and amount of the base used. With (-)-sparteine as the base, selectivities of
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 41610-6X100ML | 04061838232038 |
| 320293-PZ | 04061823810647 |
| 320293-1L | 04061826695791 |
| D186309-500ML | 04061833560969 |
| D186309-18L-C | 04061837550317 |
| D186309-4X100ML | 04061837550362 |
| 8030711000 | 04022536378114 |
| 41610-1L | 04061838127365 |
| 41610-500ML | 04061838127372 |
| 41610-100ML | 04061838127358 |
| 49497-1ML | 04061838203021 |
| 49497-10ML | 04061838196071 |
| 49497-10X1ML | 04061838196088 |
| D186309-1L | 04061833560952 |
| D186309-100ML | 04061833560938 |
| D186309-18L-KL | 04061833560945 |
| D186309-18L | 04061837550300 |
| D186309-25ML | 04061837550348 |
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