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Merck
CN

10390

1,6-Anhydro-β-D-glucose

purum, ≥98.0% (TLC)

Synonym(s):

Levoglucosan

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About This Item

Empirical Formula (Hill Notation):
C6H10O5
CAS Number:
Molecular Weight:
162.14
EC Number:
207-855-0
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
80998
MDL number:
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grade

purum

assay

≥98.0% (TLC)

optical activity

[α]20/D −66±2°, c = 10% in H2O

mp

173-183 °C, 182-184 °C (lit.)

SMILES string

O[C@H]1[C@H](O)[C@H]2CO[C@H](O2)[C@@H]1O

InChI

1S/C6H10O5/c7-3-2-1-10-6(11-2)5(9)4(3)8/h2-9H,1H2/t2-,3-,4+,5-,6-/m1/s1

InChI key

TWNIBLMWSKIRAT-VFUOTHLCSA-N

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Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Important carbohydrate derivative with interesting chemical reactivity arising from its rigid bicyclic framework. Derivatisations proceed selectively to give the 2,4-disubstituted levoglucosan, reviews; 1,6:2,3-Dianhydro-β-D-mannopyranose

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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J. Stanek et al.
Synthesis, 898-898 (1972)
P.J. Hodges et al.
Synthesis, 26, 4111-4111 (1985)
M. Czerny et al.
Advances in Carbohydrate Chemistry and Biochemistry, 34, 24-24 (1977)
Christopher T Migliaccio et al.
Environmental health perspectives, 117(1), 74-79 (2009-01-24)
Biomass smoke is an important source of particulate matter (PM), and much remains to be discovered with respect to the human health effects associated with this specific PM source. Exposure to biomass smoke can occur in one of two main
Gal Schkolnik et al.
Analytical and bioanalytical chemistry, 385(1), 26-33 (2005-12-01)
Levoglucosan is a tracer for biomass burning sources in atmospheric aerosol particles. Therefore, much effort has been recently put into developing methods for its quantification. This review describes and compares both established and emerging analytical methods for levoglucosan quantification in

Global Trade Item Number

SKUGTIN
275697-1G04061825584164

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