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About This Item
Linear Formula:
CCl3CH2OCON=NCOOCH2CCl3
CAS Number:
Molecular Weight:
380.82
PubChem Substance ID:
UNSPSC Code:
12352101
Beilstein/REAXYS Number:
2141527
MDL number:
SMILES string
ClC(Cl)(Cl)COC(=O)\N=N\C(=O)OCC(Cl)(Cl)Cl
InChI
1S/C6H4Cl6N2O4/c7-5(8,9)1-17-3(15)13-14-4(16)18-2-6(10,11)12/h1-2H2/b14-13+
InChI key
LIEOEYTUTSDYKB-BUHFOSPRSA-N
grade
purum
assay
≥97.0% (H-NMR)
storage temp.
2-8°C
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Other Notes
Stable, crystalline ester of azodicarboxylate with many advantages over other esters of this diacid: the trichloroethyl esters in reaction products can be removed under neutral conditions, the reagent is more reactive in cycloaddition reactions; electrophilic aromatic substitution to give hydrazines or amines
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Y. Leblanc et al.
Tetrahedron Letters, 30, 2889-2889 (1989)
N. Boudreault, Y. Leblanc
Organic Syntheses, 74, 241-241 (1997)
M. Kaname et al.
Tetrahedron Letters, 40, 7993 -7993 (1999)
R.D. Little et al.
Journal of the American Chemical Society, 101, 7129-7129 (1979)
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