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Merck
CN

12488

Benzo[k]fluoranthene

puriss., ≥99.0% (GC)

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About This Item

Empirical Formula (Hill Notation):
C20H12
CAS Number:
Molecular Weight:
252.31
EC Number:
205-916-6
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
1873745
MDL number:
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InChI key

HAXBIWFMXWRORI-UHFFFAOYSA-N

InChI

1S/C20H12/c1-2-6-15-12-19-17-10-4-8-13-7-3-9-16(20(13)17)18(19)11-14(15)5-1/h1-12H

SMILES string

c1ccc2cc-3c(cc2c1)-c4cccc5cccc-3c45

grade

puriss.

assay

≥99.0% (GC)

solubility

95% ethanol: <1 mg/mL at 20 °C, DMSO: <1 mg/mL at 20 °C, H2O: <1 mg/mL at 20 °C, acetone: 1-10 mg/mL at 20 °C, methanol: <1 mg/mL at 20 °C, toluene: 5-10 mg/mL at 20 °C

fluorescence

λex 306 nm; λem 411 nm in acetonitrile: water (1:1)

suitability

suitable for fluorescence

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Application

Non-carcinogenic standard in environmental research

Analysis Note

In addition to the emission maximum at 411 nm, there are lower maxima at 435 and 460 nm.

pictograms

Health hazardEnvironment

signalword

Danger

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Erin E Bessette et al.
Drug metabolism and disposition: the biological fate of chemicals, 33(3), 312-320 (2004-12-04)
Polycyclic aromatic hydrocarbons (PAHs) and heavy metals are often environmental cocontaminants that could interact to alter PAH carcinogenicity. The heavy metal, arsenite, and the PAH, benzo[k]fluoranthene, were used as prototypes to investigate, in human HepG2 cells, mechanisms whereby the bioactivation
G Verrhiest et al.
Ecotoxicology (London, England), 10(6), 363-372 (2002-01-05)
Polycyclic Aromatic Hydrocarbons (PAHs) are ubiquitous pollutants of sediments. Sediment quality criteria often use toxicity data for individual PAHs. However, PAHs always occur in field sediments as a complex mixture of compounds. In this study, the toxicity of phenanthrene (P)
Tohru Saitoh et al.
Talanta, 79(2), 177-182 (2009-06-30)
A simple and rapid method for the highly sensitive determination of polycyclic aromatic hydrocarbons (PAHs) in water was developed. Benzo[a]pyrene, benzo[k]fluoranthene, perylene, and pyrene in water were concentrated into sodium dodecyl sulfate (SDS)-alumina admicelles. The collection was performed by adding
K L Willett et al.
Toxicology and applied pharmacology, 177(3), 264-271 (2001-12-26)
Certainpolynuclear aromatic hydrocarbons (PAHs) such as benzo[a]pyrene (BaP) induce CYP1A-dependent enzyme activities. Because PAHs are ubiquitous environmental contaminants, and some are aryl hydrocarbon agonists, CYP1A has been used as a biomarker for PAH exposure. However, PAHs exist in the environment
Hiroyuki Masaki et al.
The Analyst, 130(9), 1253-1257 (2005-08-13)
We developed a device and some systems for detecting benzo[a]pyrene (B[a]P) and benzo[k]fluoranthene (B[k]F). The device uses a UV light-emitting diode that emits light with a wavelength of 370 nm and a violet laser diode that emits light with a

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