14691
Bis(1,5-cyclooctadiene)diiridium(I) dichloride
purum
Synonym(s):
1,5-Cyclooctadiene-iridium(I) chloride dimer, Chloro(1,5-cyclooctadiene)iridium(I) dimer, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium, Iridium(I) chloride 1,5-cyclooctadiene complex dimer, [Ir(1,5-cod)Cl]2, [Ir(cod)Cl]2
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About This Item
Empirical Formula (Hill Notation):
C16H24Cl2Ir2
CAS Number:
Molecular Weight:
671.70
EC Number:
235-170-7
UNSPSC Code:
12352300
MDL number:
grade
purum
mp
205 °C (dec.) (lit.), ~205 °C (dec.)
storage temp.
2-8°C
SMILES string
Cl[Ir].Cl[Ir].C1CC=CCCC=C1.C2CC=CCCC=C2
InChI
1S/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
InChI key
ZFOUDQNHNLDNLD-MIXQCLKLSA-L
Application
Starting material used for the synthesis of Ir(I)-phosphine complexes; Preparation of Ir(I)-carboxylate complexes; Isomerization of yn-ones to conjugated dienones
Metal precursor for asymmetric allylic substitutions.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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L.M. Haines et al.
J. Chem. Soc., Dalton Trans., 1891-1891 (1972)
D. Ma et al.
The Journal of Organic Chemistry, 54, 1105-1105 (1989)
Markovic, D.; Hartwig, J. F.
Journal of the American Chemical Society, 129 (2007)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 429848-5G | 04061831810912 |