15233
N,O-Bis(trimethylsilyl)hydroxylamine
purum, ≥97.0% (GC)
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About This Item
Linear Formula:
(CH3)3SiONHSi(CH3)3
CAS Number:
Molecular Weight:
177.39
EC Number:
245-188-7
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1920452
MDL number:
InChI key
ZAEUMMRLGAMWKE-UHFFFAOYSA-N
InChI
1S/C6H19NOSi2/c1-9(2,3)7-8-10(4,5)6/h7H,1-6H3
SMILES string
C[Si](C)(C)NO[Si](C)(C)C
grade
purum
assay
≥97.0% (GC)
refractive index
n20/D 1.411 (lit.)
bp
78-80 °C/100 mmHg (lit.)
density
0.83 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Other Notes
Reagent for the synthesis of O-silylated hydroxamates which can be transformed into isocyanates ; Synthesis of oximes from carbonyl compounds; Reagent for electrophilic amination; Reagent for nucleophilic hydroxylamination
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
84.2 °F - closed cup
flash_point_c
29 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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R.V. Hoffman et al.
Synthesis, 831-831 (1987)
M.T. Reetz et al.
Tetrahedron Letters, 35, 8765-8765 (1994)
T.A. Oster et al.
The Journal of Organic Chemistry, 48, 4307-4307 (1983)
A. Casarini et al.
The Journal of Organic Chemistry, 58, 5620-5620 (1993)
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