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Merck
CN

154733

Chloroform

ACS spectrophotometric grade, ≥99.8%, contains amylenes as stabilizer

Synonym(s):

Methylidyne trichloride, Trichloromethane

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About This Item

Empirical Formula (Hill Notation):
CHCl3
CAS Number:
Molecular Weight:
119.38
EC Number:
200-663-8
UNSPSC Code:
12191502
PubChem Substance ID:
Beilstein/REAXYS Number:
1731042
MDL number:
Assay:
≥99.8%
Grade:
ACS spectrophotometric grade
Technique(s):
UV/Vis spectroscopy: suitable
Bp:
60.5-61.5 °C (lit.)
Vapor pressure:
160 mmHg ( 20 °C)
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grade

ACS spectrophotometric grade

vapor density

4.1 (vs air)

vapor pressure

160 mmHg ( 20 °C)

assay

≥99.8%

form

liquid

contains

amylenes as stabilizer

packaging

glass bottle of 2 L

technique(s)

UV/Vis spectroscopy: suitable

impurities

Acetone and aldehyde, passes test, Acid and chloride, passes test, Free chlorine (Cl), passes test, ≤0.03% water

evapn. residue

<0.001%

color

APHA: ≤10

refractive index

n20/D 1.445 (lit.)

bp

60.5-61.5 °C (lit.)

mp

−63 °C (lit.)

density

1.492 g/mL at 25 °C

cation traces

Pb: ≤0.05 ppm

λ

H2O reference

UV absorption

λ: 245 nm Amax: 1.00, λ: 255 nm Amax: 0.25, λ: 260 nm Amax: 0.15, λ: 270 nm Amax: 0.05, λ: 290-400 nm Amax: 0.01

SMILES string

ClC(Cl)Cl

InChI

1S/CHCl3/c2-1(3)4/h1H

InChI key

HEDRZPFGACZZDS-UHFFFAOYSA-N

Other Notes

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.


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pictograms

Skull and crossbonesHealth hazard

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 - STOT SE 3

target_organs

Central nervous system, Liver,Kidney

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

does not flash

flash_point_c

does not flash

ppe

Eyeshields, Faceshields, Gloves

Regulatory Information

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Photophysics of closed-and open-ring isomers of a diarylethene with a carboxylic anchor group.
Kuehn S, et al.
Chemical Physics Letters, 542, 94-98 (2012)
High activity and regenerability of a palladium-gold catalyst for chloroform degradation.
Velazquez JC, et al.
Journal of Chemical Technology and Biotechnology (2015)
Yongjun Liu et al.
Journal of hazardous materials, 308, 84-90 (2016-01-26)
In this study, efficient dechlorination and decomposition of chloroform (CF) induced by glow discharge plasma (GDP) in contact with a sodium sulfate solution was investigated. Intermediate byproducts were determined by ionic chromatography and headspace gas chromatography, respectively. Results showed that