15575
9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution
purum, ~0.5 M in hexane
Synonym(s):
9-BBN triflate solution, 9-BBN·CF3SO3, 9-[[(Trifluoromethyl)sulfonyl]oxy]-9-borabicyclo[3.3.1]nonane
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About This Item
Empirical Formula (Hill Notation):
C9H14BF3O3S
CAS Number:
Molecular Weight:
270.08
PubChem Substance ID:
UNSPSC Code:
12352000
Beilstein/REAXYS Number:
995656
MDL number:
grade
purum
reaction suitability
reagent type: reductant
concentration
~0.5 M in hexane
SMILES string
FC(F)(F)S(=O)(=O)OB1C2CCCC1CCC2
InChI
1S/C9H14BF3O3S/c11-9(12,13)17(14,15)16-10-7-3-1-4-8(10)6-2-5-7/h7-8H,1-6H2/t7-,8+
InChI key
NXHUKDCGEGEZCX-OCAPTIKFSA-N
Application
Reactant for:
- Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene
- Mukaiyama aldol addition
- Preparation of porphyrin dimethyldioxanyl tolyl derivative complex
- Preparation of palladium porphyrin complexes
- Boron-mediated β-alkoxy Me ketone aldol addition reactions
- Enolization agent
Other Notes
Reagent used for the formation of enol borinates from carbonyl compounds employed in stereoselective aldol reactions
Regulatory Information
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Journal of the American Chemical Society, 103, 1568-1568 (1981)
S. Massamune et al.
Journal of the American Chemical Society, 103, 1566-1566 (1981)
T. Inoue et al.
Bulletin of the Chemical Society of Japan, 53, 174-174 (1980)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 00496-5ML | 04061838603722 |