17281
1-(Pentafluoropropionyl)imidazole
derivatization grade (GC derivatization), ≥98.5%
Synonym(s):
PFPI, 1-(Perfluoropropionyl)imidazole
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About This Item
Empirical Formula (Hill Notation):
C6H3F5N2O
CAS Number:
Molecular Weight:
214.09
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
41116105
EC Number:
275-944-1
MDL number:
grade
derivatization grade (GC derivatization)
Quality Level
assay
≥98.5% (GC), ≥98.5%
reaction suitability
reagent type: derivatization reagent
reaction type: Esterifications
technique(s)
GC/MS: suitable
refractive index
n20/D 1.399
density
1.4 g/mL at 20 °C (lit.)
storage temp.
−20°C
SMILES string
FC(F)(F)C(F)(F)C(=O)n1ccnc1
InChI
1S/C6H3F5N2O/c7-5(8,6(9,10)11)4(14)13-2-1-12-3-13/h1-3H
InChI key
VZUSRIIEPFQBNE-UHFFFAOYSA-N
General description
Derivatization before a GC analysis helps in yielding distinctive products, which can be achieved using a derivatizing reagent that reacts with amino and hydroxyl functionalities quantitatively. 1-(Pentafluoropropionyl)imidazole (PFPI) is a derivatizing reagent which was found to give high yield of products than pentafluoropropionic anhydride during preparation of methyl ester/pentafluoropropionyl derivatives.
Application
PFPI may be used to incubate the lyophilized samples, for derivatization during GC/MS analysis to measure total d-chiro-Inositol content absorbed by rodents.
Other Notes
Derivatization agent for alcohols and carboxylic acids, etc. in GC
Reagent for methyl ester, pentafluoropropionyl.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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F. Karoum et al.
Biomedical Mass Spectrometry, 2, 183-183 (1975)
J.T. Etse et al.
Journal of Natural Products, 51, 314-314 (1988)
F Karoum et al.
British journal of pharmacology, 56(4), 403-411 (1976-04-01)
1 Mass fragmentography was used to measure whole brain concentrations of some of the major metabolites of tyramine, octopamine, dopamine and noradrenaline in acutely treated and in ethanol-dependent rats. 2 Treatments with ethanol, either acutely or chronically, failed to alter