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Merck
CN

17403

2,3-Dihydroxy-biphenyl

derivatization grade (GC derivatization), LiChropur™, ≥98.0%

Synonym(s):

2,3-Biphenyldiol, 3-Phenylpyrocatechol

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About This Item

Empirical Formula (Hill Notation):
C12H10O2
CAS Number:
1133-63-7
Molecular Weight:
186.21
PubChem Substance ID:
329751537
UNSPSC Code:
41116105
Beilstein/REAXYS Number:
1869593
MDL number:
MFCD00155166

Key Documents

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SMILES string

Oc1cccc(-c2ccccc2)c1O

InChI

1S/C12H10O2/c13-11-8-4-7-10(12(11)14)9-5-2-1-3-6-9/h1-8,13-14H

InChI key

YKOQAAJBYBTSBS-UHFFFAOYSA-N

grade

derivatization grade (GC derivatization)

assay

≥98.0% (HPLC), ≥98.0%

form

solid

quality

LiChropur™

reaction suitability

reagent type: derivatization reagent
reaction type: Alkylations

technique(s)

gas chromatography (GC): suitable

mp

108-113 °C

Quality Level

100

General description

Derivatization before a GC analysis helps in yielding distinctive products, which can be achieved using a derivatizing reagent that reacts with amino and hydroxyl functionalities quantitatively. 2,3-Dihydroxy-biphenyl (2,3-DHBP) is a derivatizing reagent.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
063681/1

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Ang Li et al.
Journal of environmental sciences (China), 21(2), 211-217 (2009-05-01)
A novel biphenyl-degrading bacterial strain LA-4 was isolated from activated sludge. It was identified as Dyella ginsengisoli according to phylogenetic similarity of 16S rRNA gene sequence. This isolate could utilize biphenyl as sole source of carbon and energy, which degraded
Beatriz Cámara et al.
Environmental microbiology, 6(8), 842-850 (2004-07-15)
The degradation of polychlorobiphenyls (PCBs) by diverse bacteria, including Burkholderia sp. LB400, is incomplete with a concomitant accumulation of metabolic intermediates. In this study, the toxicity of diverse (chloro)biphenyls and of their biotransformation into the first two metabolic intermediates of
Min Gou et al.
Biotechnology letters, 34(1), 117-123 (2011-09-08)
A 2,3-dihydroxybiphenyl-1,2-dioxygenase gene (designated as bphC_meta) was identified in activated sludge metagenome by PCR. This gene shared 99% sequence identity with BphC from Burkholderia xenovorans LB400. The enzyme was purified from recombinant Escherichia coli with a subunit molecular mass of
Shujuan Wang et al.
Analytical and bioanalytical chemistry, 410(27), 7145-7152 (2018-09-02)
In this work, we report a zeolitic imidazolate framework (ZIF-67) which could catalyze 3,3',5,5'-tetramethylbenzidine (TMB) to produce a yellow chromogenic reaction. ZIF-67 showed high peroxidase-like activity compared with copper-based metal-organic framework nanoparticles (Cu-MOF), zinc-based metal-organic framework nanoparticles (ZIF-8), and horseradish
Nobuyuki Sato et al.
Journal of molecular biology, 321(4), 621-636 (2002-09-11)
BphC derived from Pseudomonas sp. strain KKS102 is an extradiol-cleaving catecholic dioxygenase. This enzyme contains a non-heme iron atom and plays an important role in degrading biphenyl/polychlorinated biphenyls (PCBs) in the microbe. To elucidate detailed structures of BphC reaction intermediates
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