17618
2-Bromomethyl-1,3-dioxolane
purum, ≥95.5% (GC)
Synonym(s):
Bromoacetaldehyde ethylene acetal
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Empirical Formula (Hill Notation):
C4H7BrO2
CAS Number:
Molecular Weight:
167.00
EC Number:
224-443-6
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
103309
MDL number:
grade
purum
assay
≥95.5% (GC)
refractive index
n20/D 1.482
bp
80-82 °C/27 mmHg (lit.)
density
1.613 g/mL at 25 °C (lit.)
SMILES string
BrCC1OCCO1
InChI
1S/C4H7BrO2/c5-3-4-6-1-2-7-4/h4H,1-3H2
InChI key
CKIIJIDEWWXQEA-UHFFFAOYSA-N
Application
2-Bromomethyl-1,3-dioxolane was used in the synthesis of 1,4-benzoxazepine (BZO) derivatives. It was also used in the preparation of Grignard reagent.
Other Notes
Useful synthon for the preparation of α,β-unsaturated aldehydes; Synthon, for the preparation of 1,4-dialdehyde monoacetals
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
143.6 °F - closed cup
flash_point_c
62 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
T.M. Cresp et al.
Journal of the Chemical Society. Perkin Transactions 1, 39-39 (1974)
Schmeichel M and Redlich H.
Synthesis, 1996(08), 1002-1006 (1996)
J.F. Borgne, et al. et al.
Tetrahedron Letters, 1379-1379 (1976)
K Kamei et al.
Bioorganic & medicinal chemistry letters, 11(4), 595-598 (2001-03-07)
A series of new 3-substituted-4-(4-aminobutyl)-1,4-benzoxazepin-5(4H)-one derivatives (1-5) which showed a very high affinity for 5-HT1A receptor with good selectivity over dopamine D2 receptor was synthesized. Among these compounds, 3-chloro-4-[4-[4-(2-pyridinyl)-1,2,3,6-tetrahydropyridin-1-yl]butyl]-1,4-benzoxazepin-5(4H)-one (5: SUN N4057) exhibited remarkable neuroprotective activity in a transient middle
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service