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Merck
CN

17878

Bromoform

puriss., ≥99.0% (GC)

Synonym(s):

Tribromomethane

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About This Item

Empirical Formula (Hill Notation):
CHBr3
CAS Number:
Molecular Weight:
252.73
EC Number:
200-854-6
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1731048
MDL number:
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InChI key

DIKBFYAXUHHXCS-UHFFFAOYSA-N

InChI

1S/CHBr3/c2-1(3)4/h1H

SMILES string

BrC(Br)Br

vapor density

8.7 (vs air)

vapor pressure

5 mmHg ( 20 °C)

grade

puriss.

assay

≥99.0% (GC)

contains

~0.05% amylene as stabilizer

refractive index

n20/D 1.595 (lit.), n20/D 1.596

bp

146-150 °C (lit.)

mp

5-8 °C (lit.)

solubility

H2O: soluble, acetone: miscible, alcohol: miscible, benzene: miscible, chloroform: miscible, diethyl ether: miscible

density

2.89 g/mL at 25 °C (lit.)

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General description

Polar ordering induced by pressure in bromoform has been determined using single-crystal X-ray diffraction.

Application

Bromoform was used to carry out the risk assessment of tribromomethane in drinking water.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

106.3 °F - closed cup - (own results)

flash_point_c

41.3 °C - closed cup - (own results)

Regulatory Information

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Kamil F Dziubek et al.
The journal of physical chemistry. B, 112(38), 12001-12009 (2008-08-02)
Polar ordering has been induced by pressure in solid chloroform (trichloromethane), CHCl3, and bromoform (tribromomethane), CHBr3, obtained by isochoric and isothermal freezing in a diamond anvil cell. Structures of these new polymorphs have been determined by single-crystal X-ray diffraction, CHCl3
Nasrul Hamidin et al.
Water research, 42(13), 3263-3274 (2008-06-03)
The presence of chlorinated disinfection by-products (DBPs) in drinking water is a public health issue, due to their possible adverse health effects on humans. To gauge the risk of chlorinated DBPs on human health, a risk assessment of chloroform (trichloromethane
David R Geter et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 43(9), 1405-1412 (2005-06-01)
Folate and folic acid are forms of the B vitamin that are involved in the synthesis, repair, and functioning of DNA and are required for the production and maintenance of cells. Low levels of folate have been associated with several
S K Pal et al.
The Journal of chemical physics, 138(12), 124501-124501 (2013-04-06)
Ultrafast deep-ultraviolet through near infrared (210-950 nm) transient absorption spectroscopy complemented by ab initio multiconfigurational calculations offers a global description of the photochemical reaction pathways of bromoform following 255-nm excitation in methylcyclohexane and acetonitrile solutions. Photoexcitation of CHBr3 leads to
Stacey L Carrier et al.
The journal of physical chemistry. A, 114(3), 1548-1555 (2009-12-09)
Ultrafast photolysis of bromoform (CHBr(3)) with a 267 nm pulse of light followed by broadband transient electronic absorption identifies the photoproducts and follows their evolution in both neat bromoform and cyclohexane solutions. In neat bromoform, a species absorbing at 390

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