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Merck
CN

18298

5-Bromopyrimidine

purum, ≥97.0% (GC)

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About This Item

Empirical Formula (Hill Notation):
C4H3BrN2
CAS Number:
Molecular Weight:
158.98
EC Number:
224-992-1
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
107326
MDL number:
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grade

purum

assay

≥97.0% (GC)

mp

67-73 °C (lit.)

SMILES string

Brc1cncnc1

InChI

1S/C4H3BrN2/c5-4-1-6-3-7-2-4/h1-3H

InChI key

GYCPLYCTMDTEPU-UHFFFAOYSA-N

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Application

5-Bromopyrimidine was used in the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives.

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Xiaofeng Rao et al.
Organic & biomolecular chemistry, 10(39), 7875-7883 (2012-08-15)
A palladium-catalyzed aerobic and ligand-free Suzuki reaction in aqueous ethanol has been developed for the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives. A number of N-heteroaryl halides, namely 2-halogenated pyridines, 2-bromoquinoline, 5-bromopyrimidine and 2-chloropyrazine, were coupled with 4-(9H-carbazol-9-yl)phenylboronic acid (CPBA) or

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