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About This Item
Empirical Formula (Hill Notation):
C4H3BrN2
CAS Number:
Molecular Weight:
158.98
EC Number:
224-992-1
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
107326
MDL number:
grade
purum
assay
≥97.0% (GC)
mp
67-73 °C (lit.)
SMILES string
Brc1cncnc1
InChI
1S/C4H3BrN2/c5-4-1-6-3-7-2-4/h1-3H
InChI key
GYCPLYCTMDTEPU-UHFFFAOYSA-N
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Application
5-Bromopyrimidine was used in the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives.
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Xiaofeng Rao et al.
Organic & biomolecular chemistry, 10(39), 7875-7883 (2012-08-15)
A palladium-catalyzed aerobic and ligand-free Suzuki reaction in aqueous ethanol has been developed for the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives. A number of N-heteroaryl halides, namely 2-halogenated pyridines, 2-bromoquinoline, 5-bromopyrimidine and 2-chloropyrazine, were coupled with 4-(9H-carbazol-9-yl)phenylboronic acid (CPBA) or
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