19667
Butylboronic acid
derivatization grade (GC derivatization), LiChropur™, ≥96.0% (T)
Synonym(s):
1-Butaneboronic acid
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About This Item
Linear Formula:
CH3(CH2)3B(OH)2
CAS Number:
Molecular Weight:
101.94
UNSPSC Code:
41116105
NACRES:
NA.22
PubChem Substance ID:
EC Number:
224-607-7
Beilstein/REAXYS Number:
1733489
MDL number:
InChI key
QPKFVRWIISEVCW-UHFFFAOYSA-N
InChI
1S/C4H11BO2/c1-2-3-4-5(6)7/h6-7H,2-4H2,1H3
SMILES string
CCCCB(O)O
grade
derivatization grade (GC derivatization)
assay
≥96.0% (T)
quality
LiChropur™
reaction suitability
reagent type: derivatization reagent
reaction type: Alkylations
technique(s)
gas chromatography (GC): suitable
Quality Level
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Related Categories
Application
- Developing a reference measurement procedure for free glycerol in human serum by two-step gas chromatography-isotope dilution mass spectrometry.: This research employs butylboronic acid in a reference measurement procedure to quantify free glycerol in human serum. The method is significant for clinical diagnostics, providing accurate and reliable measurements for metabolic studies (Chen et al., 2015).
Other Notes
Derivatizing agent for gas chromatography
Reagent for butylboronate.
Suitable for the derivatization of proximal difunctional compounds (a- and β-hydroxyacids; Ο-phenolic acids; enolizable a-oxo acids; 1,2- and 1,3-diols; enolizable 1,2- and 1,3-ketols; β- and γ-hydroxyamines).
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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A. Darbre et al.
Handbook of Derivatives for Chromatography (1970)
G E Joannou et al.
Steroids, 61(1), 11-17 (1996-01-01)
We report the synthesis of 3 beta,15 beta,17 alpha-trihydroxy-5-pregnen-20- one (1) from 3 beta,15 beta-dihydroxy-5,16-pregnadien-20-one (11) in 7 steps using boronate derivatives as a means of protecting the 17,20-glycol side-chain of steroid intermediates. 16 alpha,17 alpha-Epoxy-3 beta,15 beta-dihydroxy-5- pregnen-20-one (12)
Measurement of myo-inositol in diabetic sera by GC/MS/SIM using n-butylboronate derivatives.
M Hasegawa et al.
Clinica chimica acta; international journal of clinical chemistry, 176(2), 207-212 (1988-08-31)
B Bennett et al.
Biochemistry, 36(32), 9837-9846 (1997-08-12)
The Co(II)Zn(II)- and Zn(II)Co(II)-substituted derivatives of the aminopeptidase from Aeromonas proteolytica (AAP) were probed by EPR spectroscopy. EPR spectra of the high-spin S = 3/2 Co(II) ions in [CoZn(AAP)] and [ZnCo(AAP)] indicated that each metal binding site provides a spectroscopically
Determination of meprobamate as an n-butylboronate ester derivative in serum by gas-liquid chromatography.
B Johansson et al.
Journal of chromatography, 341(2), 462-464 (1985-06-14)
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