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Merck
CN

19917

5-O-(tert-Butyldimethylsilyl)-2,3-O-isopropylidene-D-ribonic acid γ-lactone

purum, ≥98.0% (sum of enantiomers, GC)

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About This Item

Empirical Formula (Hill Notation):
C14H26O5Si
CAS Number:
Molecular Weight:
302.44
UNSPSC Code:
12352200
Beilstein/REAXYS Number:
4296295
MDL number:
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purum

assay

≥98.0% (sum of enantiomers, GC)

optical activity

[α]20/D −47±2°, c = 0.8% in chloroform

mp

72-74 °C (lit.)

SMILES string

CC(C)(C)[Si](C)(C)OC[C@H]1OC(=O)[C@@H]2OC(C)(C)O[C@H]12

InChI

1S/C14H26O5Si/c1-13(2,3)20(6,7)16-8-9-10-11(12(15)17-9)19-14(4,5)18-10/h9-11H,8H2,1-7H3/t9-,10-,11-/m1/s1

InChI key

VBPYRQYBEKHPKA-GMTAPVOTSA-N

Other Notes

Carbohydrate chiral building block; synthesis of nucleosides and analogues; Other applications

Regulatory Information

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T.V. RajanBabu et al.
Journal of the American Chemical Society, 110, 7128-7128 (1988)
W.B. Motherwell et al.
Journal of the Chemical Society. Chemical Communications, 1437-1437 (1989)
K. Pankiewicz et al.
The Journal of Organic Chemistry, 53, 3473-3473 (1988)
J.S. Houlten et al.
Tetrahedron, 49, 8087-8087 (1993)
J.A. Piccirilli et al.
Helvetica Chimica Acta, 74, 397-397 (1991)

Global Trade Item Number

SKUGTIN
95755-1ML04061836828202

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